真空感应及电熔镍高温合金中微量元素的控制

G. Durber, M. Boneham
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引用次数: 11

摘要

摘要对镍高温合金中不需要的微量元素进行了分类,介绍了分析检测的先进方法。这些微量元素的分析技术的改进,加上更严格的用户操作要求,在过去十年中导致了材料规格的逐步收紧。根据“最先进”生产商的经验,讨论了镍高温合金熔炼实践中这些元素的控制,以及原材料选择的重要性。在作者的公司,用于铸造重熔棒和锻造合金制造的原始原料中微量元素的水平是详细的,以及与从铸造厂和最终用户回收废料有关的问题。讨论了真空电弧重熔、电渣重熔和电子束重熔在化学精炼方面的效果,并与真空感应重熔进行了对比。
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Trace element control in vacuum induction and consumable–electrode melted Ni superalloys
AbstractUndesirable trace elements in Ni superalloys are classified, and the advanced methods of analytical detection described. The improvement in analytical techniques for these trace elements, together with more stringent user operating demands, has resulted in a progressive tightening of material specifications over the past decade. Control of these elements in Ni superalloy melting practice based on ‘state of the art’ producer experience is discussed, together with the importance of raw material selection. The levels of trace elements in virgin raw materials, as used for cast remelt bar and wrought alloy manufacture in the authors' company, are detailed, together with the problems associated with the recycling of scrap from foundries and end users. The effectiveness of secondary melting by vacuum arc remelting, electroslag remelting, and electron-beam remelting, in terms of chemical refinement, is discussed and contrasted with that of vacuum induction melting.
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