聚丙烯酸水凝胶珠去除(水晶紫,Janus绿)染料

N. M Ali
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引用次数: 0

摘要

当使用聚丙烯酸珠作为表面时,涉及到水晶紫(C.V)和双面绿(J.G)染料的去除。除了混合染料外,还研究了该过程的等温线,以及影响等温线的因素(温度、离子强度、振荡效应、干珠效应)。结果表明,两种染料的吸附更符合友好方程,而不是Temkin和Langmuir方程。吸附量与温度的升高呈正相关关系,吸附量随温度的升高而增加。在温度(20c)下加入盐,吸附量增加。此外,有一个小的变化,当使用湿珠聚丙烯酸。与不摇水浴相比,摇水浴时吸附量增加。通过热力学函数(H, G, S)的研究,说明了该过程是发射或吸收过程,也是自发和随机过程。研究了一级拉格伦方程和二级拉格伦方程的动力学参数,根据实验结果,数据表明吸附不仅服从一级方程,而且服从准二级方程。
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Removal of (Crystal Violet, Janus Green) dyes by poly acrylic acid hydrogel beads
     Removal of Crystal Violet (C.V) and Janus Green (J.G) dyes was involved when using poly acrylic beads as a surface. The Isotherm of the process were studied and factor that influence  it such as (Temperature, ionic strength , Shaking effect , effect of dry beads ) in addition to mixing  dyes . According to the results it has been found that the adsorption of the two dyes is matched of the friendlish equation more than the Temkin and Langmuir equation. there is an  a positive relationship between the adsorption and increasing of temperature found that the adsorption increasing when the temperature increase . the adsorption increased when the salt added at temperature (20C0). Also, There is a small change when used a wet beads of poly acrylic. adsorption is increasing at shaking when we compare with no shaking of water bath. thermodynamic function were studied (?H,?G,?S) to explain that the process are emitter or absorbent also spontaneous and the random of the process . a kinetic parameter has been studied Lagergren equation ( first order) and by (second order) equations, depending to the results of the experimental, data shown us that the adsorption obeys the pseudo-second order furthermore the first-order equation .
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