用碳玻璃电极(CGE)在KCl水溶液中测定19.1℃时CuCl2与橙G (OG)的相互作用参数

E. A. Gomaa, M. Diab, A. El-Sonbati, Hamed M Abulenader, A. Helmy
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引用次数: 2

摘要

采用碳玻璃电极(CGE),在19.1℃条件下,研究了无橙G (OG)和有橙G (OG)情况下氯化铜的氧化还原机理。采用0.1 M KCl作为支撑电解质,研究了CuCl2单独和配体为橘色G (OG)时氧化还原反应扫描速率的影响。用不同的热化学数据对CuCl2+橙G (OG)相互作用形成的络合物的稳定性常数进行了评价。用橙色G (OG)考察了不同扫描速率对氯化铜在配体缺失和存在情况下的影响。不同的扫描使用0.1,0.05,0.02和0.01 V/秒。同时计算了CuCl2与橙G (OG)在0.1MKCl负载电解质中相互作用的稳定常数和Gibbs自由能。
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Interaction Parameters for CuCl2 Plus Orange G (OG) at 19.1oC Using Carbon Glassy Electrode (CGE) in KCl Aqueous Solutions
The redox mechanisms were examined for copper chloride in absence and presence of Orange G (OG) at 19.1°C using Carbon glassy electrode (CGE). The supporting electrolyte used is 0.1 M KCl effect of scan rate was also studies for the redox reactions for CuCl2 alone and in presence of the ligand used orange G (OG). Stability constants for the complex formed from the interaction of CuCl2+ Orange G (OG) were evaluated with the different thermo chemical data. Effect of different scan rates were examined for cupric Chloride in absence and presence of the ligand used Orange G (OG).The different scans used are 0.1, 0.05, 0.02 and 0.01 V/Sec. The stability constants and Gibbs free energies of complexation were also estimated for the interaction of CuCl2 with Orange G (OG) in 0.1MKCl supporting electrolyte.
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