菲律宾梅科亚延河土壤和表层沉积物重金属污染及其与环境指标的关系

Reymar R. Diwa, C. Deocaris, A. Orbecido, A. Beltran, E. Vallar, M. Galvez, L. Belo
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摘要

迈科亚延市是菲律宾的工业重镇。由于工业向环境排放有毒物质,它被认为是发展中国家污染最严重的城市之一。本研究通过对梅卡延河流域土壤和沉积物样品中铬(Cr)、汞(Hg)、镍(Ni)、铅(Pb)等重金属的分析,以及对梅卡延河流域总氮(TN)、总有机质(TOM)、总磷(TP)等环境指标的分析,探讨了梅卡延河流域重金属污染的来源。采用层次聚类分析(HCA)、主成分分析(PCA)和Pearson相关分析(CA)确定金属来源。我们的研究结果显示了由于工业活动的集中,黄河下游重金属污染严重的位置。铬是由于大量的制革厂将未经处理的废水排放到河流中。铅酸电池回收和黄金冶炼行业对铅和汞的投入也很大。风险评估还表明,在工业活动集中的地区,重金属污染程度严重。研究结果表明,重金属对土壤和沉积物中K、TN、TOM和TP具有相似的影响。我们的研究表明,除了当地政府正在进行的固体废物清理工作之外,还迫切需要解决Meycauayan的重金属污染问题。
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Heavy Metal Pollution in Soil and Surface Sediments of Meycauayan River, Philippines and Their Relationship to Environmental Indicators
ABSTRACT The City of Meycauayan is an industrial powerhouse in the Philippines. It is considered as one of the most polluted cities in the developing world on the account of industrial discharges of toxic materials to the environment. This work investigated the sources of the heavy metal pollution in Meycauayan by analyzing soil and sediment samples for heavy metals like Chromium (Cr), Mercury (Hg), Nickel (Ni), and Lead (Pb) together with selected environmental indicators such as Total Nitrogen (TN), Total Organic Matter (TOM), and Total Phosphorus (TP) located along the Meycauayan River. Hierarchical cluster analysis (HCA), principal components analysis (PCA), and Pearson correlation analysis (CA) were used to identify the sources of the metals. Our results show delineated locations of severe levels of heavy metal pollution downstream of the river because of the concentration of industrial activities. Cr is due to proliferation of tanneries discharging untreated wastewaters to the river. Significant input of Pb and Hg from Pb-acid battery recycling and gold smelting industries were also found. The risk assessments also indicate severe levels of heavy metal pollution in locations where industrial activities are concentrated. Our findings indicate that the heavy metals have similar impacts to K, TN, TOM, and TP in the soil and sediments. Our study shows the serious need to address heavy metal pollution in Meycauayan aside from the ongoing cleanup of solid wastes as part of rehabilitation efforts by the local government.
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