叶绿素光反应中心模型的252Cf-PDMS

J.E. Hunt, T.J. Michalski, J.J Katz
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引用次数: 4

摘要

采用252cf -等离子解吸质谱(PDMS)对化学修饰的叶绿素和卟啉进行了研究。薄膜的252Cf-PDMS光谱显示出强烈的分子离子和断裂,从而可以合理地进行化合物鉴定。讨论了二(10-羟基丁氧基-甲基苯酚a)-1,4-二氯膦酸酯和线性二(四苯基卟啉)两种化合物的252Cf-PDMS。
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252Cf-PDMS of chlorophyll photoreaction center models

Chemically modified chlorophylls and porphyrins have been studied by 252Cf-plasma desorption mass spectrometry (PDMS). The 252Cf-PDMS spectra of thin films show intense molecular ions and fragmentation from whicn we make reasonable assignments for compound identification. The 252Cf-PDMS of two compounds, bis(10-hydroxybutoxy-methyl pheophorbide a)-1,4-dichlorophtalate and linear bis(tetraphenylporphyrin) are discussed.

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Editorial Subject index Author index High resolution accurate mass measurements of FAB-generated ions by use of peak matching and multichannel analyzer techniques. Secondary ion mass spectrometry of low-temperature solids
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