维生素c对电抛光钢形貌和光学性能的影响

F. Abouzeid
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摘要

采用动电位极化法研究了钢在正磷酸中的电化学抛光过程。电解抛光在含有维生素C的溶液中进行。在电解抛光溶液中加入维生素C可以降低极限电流。建立了维生素C浓度对电抛光过程和表面织构的影响(AFM, SEM)和UV-VIS-NIR光谱。结果表明:随着维生素C浓度从2 × 10-5增加到5 × 10-5 M,钢试样的粗糙度和反射率分别减小和增大;当浓度增加到10 × 10-5 M时,则出现相反的趋势。电抛光前钢试样的粗糙度为236.7 nm,在5 × 10-5 M维生素c的存在下,电抛光后钢试样的粗糙度降至140 nm。扫描电镜研究证实,低浓度和中等浓度的维生素C比高浓度的维生素C更能有效地提高水平和亮度。关键词:钢,电抛光,维生素C,扫描电镜,原子力显微镜,反射率。
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A study of the morphology and optical properties of electro polished steel in the presence of Vitamin-C
The studies of steel electrochemical polishing Electropolishing (EP) in orthophoshoric acid were performed by potentiodynamic polarization. Electropolishing was conducted in solution containing Vitamin C. Addition of Vitamin C to electropolishing solution results in a lower limiting current. Vitamin C concentration influence on electropolishing process and surface texture (AFM, SEM) and UV-VIS-NIR Spectroscopy was established. The results show that by increasing Vitamin C concentration from 2 × 10-5 to 5 × 10-5 M, roughness and reflectance of steel specimens decrease/increase respectively. The opposite trend is seen when the concentration increases to 10 × 10-5 M. The roughness of steel specimen before electropolishing is 236.7 nm and it will decrease to 140 nm by electropolishing in the presence of 5 × 10-5 M Vitamin C. A similar trend is also seen in reflection. The SEM study confirms that low and moderate concentration of Vitamin C was effective to enhance levelling and brightness more than higher concentrations.   Key words: Steel, electropolishing, Vitamin C, scanning electron microscope (SEM), atomic force microscope (AFM), reflectance.
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