二氧化钛(TiO2)和Mg-TiO2纳米颗粒光催化降解有机染料

Sandesh V. Jaybhaye, Nikita Shinde, Shrutika Jaybhaye, H. Narayan
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引用次数: 4

摘要

以榕叶提取物为原料,以四氯化钛为前驱物,采用绿色法合成了二氧化钛基纳米光催化剂。以氯化镁为原料,采用化学沉淀法对二氧化钛进行了掺杂。通过CPS圆盘离心机、衍射光散射(DLS)和场发射枪扫描电镜(fg - sem)技术对NPC样品的大小进行了估计和表征。采用紫外可见光谱法研究了NPCs的光催化性能。制备了一种低成本、简单的光反应器,研究了甲基橙(MO)和亚甲基蓝(MB)染料溶液的光催化降解。在npc的存在下,观察到染料的合理降解。因此,本文研究的NPCs在可见光下降解MO和MB染料是一种很有前途的纳米材料。然而,需要对影响所涉及过程的各种因素进行详细调查,以优化条件,以达到最佳的降解效率。
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Photocatalytic Degradation of Organic Dyes Using Titanium Dioxide (TiO2) and Mg-TiO2 Nanoparticles
Titanium dioxide (TiO 2 ) based nano-sized photocatalysts (NPCs) were synthesized following a green method from the extract of Peepal ( Ficus religiosa ) leaves and titanium tetrachloride as precursors. Doping of TiO 2 with Magnesium (Mg) was done using magnesium chloride through the method of chemical precipitation. Size of the NPC samples were estimated and characterized by CPS Disc Centrifuge, Diffracted Light Scattering (DLS) and Field Emission Gun Scanning Electron Microscopy (FEG-SEM) techniques. UV-visible spectroscopy was employed in the study of photocatalytic properties of the NPCs. A low-cost, simple photo-reactor was fabricated and photocatalytic degradation of Methyl Orange (MO) and Methylene Blue (MB) dye solutions was investigated. Reasonable degradation of the dyes was observed in the presence of the NPCs. It was therefore concluded that the NPCs studied in this work can be promising nanomaterials for the degradation of MO and MB dyes under visible light irradiation. Nevertheless, a detailed investigation of various factors influencing the processes involved will be required to optimize the conditions in order to achieve the best degradation efficiency.
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