绿色条件下纳米铁氧体铜催化合成-氨基腈

A. Gharib, N. Pesyan, L. V. Fard, M. Roshani
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引用次数: 10

摘要

铁氧体铜纳米材料作为可重复使用的非均相引发剂在α-氨基腈合成中的应用。纳米催化剂易于回收,并记录了其可重复使用性。研究了以纳米铁氧体铜为催化剂,在室温和绿色溶剂(水为溶剂)条件下,不同醛类与胺类和三甲基硅氰化物一锅反应合成α-氨基腈衍生物。α-氨基腈在制备各种氨基酸、酰胺、二胺和含氮杂环中起着重要作用。
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Catalytic Synthesis of -Aminonitriles Using Nano Copper Ferrite under Green Conditions
Copper ferrite nanomaterial as reusable heterogeneous initiator in the synthesis of α-aminonitriles. The nanocatalyst is easily recovered and its reusability is recorded. Synthesis of α-aminonitriles derivatives by one-pot reaction of different aldehydes with amines and trimethylsilyl cyanides has been developed using nano copper ferrite catalyst under room temperature and green solvent (water as solvent) conditions. α-aminonitriles are important in preparing a wide variety of amino acids, amides, diamines, and nitrogen containing heterocycles.
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