氰金刚烷的“玻璃状”和塑性晶体:布里渊散射研究

J. Bonnet, M. Boissier, J. Pelous, R. Vacher, Pl. E. Bataillon, Montpellier Cédex, France M. Descamps, J. L. Sauvajol
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引用次数: 3

摘要

测定了氰金刚烷在塑性和玻璃晶相的弹性常数。特别注意了c11的温度演化以及相应模态的阻尼。与中子的结果比较表明,在室温下色散较强。通过建立分子的局部反铁序,解释了c11在塑性相中的温度依赖性。单晶中心80 ~ 435 K扩散布里渊常数的测定。变热系数c11与衰减模对应。中子扩散特性的比较:温度环境下强色散的存在性。非有序分子局部型反铁的相变热敏法解释
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« Glassy » and plastic crystals of cyanoadamantane : a Brillouin scattering investigation
The elastic constants of cyanoadamantane have been measured in the plastic and «glassy» crystal phases. A special attention has been given to the temperature evolution of C 11 as well as to the damping of the corresponding mode. Comparison with neutron results shows a strong dispersion at room temperature. The temperature dependence of C 11 in the plastic phase has been explained by the setting-up of a local antiferro ordering of molecules Determination des constantes d'elasticite d'apres les mesures de diffusion Brillouin sur monocristal entre 80 et 435 K. Variation thermique de C 11 et attenuation du mode correspondant. Comparaison aux donnees de diffusion de neutrons: existence d'une forte dispersion a temperature ambiante. Explication de la variation thermique de C 11 en phase plastique par apparition d'un ordre moleculaire local de type antiferro
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