P (VDF-TrFE)/离子液体凝胶的结构和压电特性

M. Fukagawa, Y. Koshiba, M. Morimoto, Tatsuya Fukushima, K. Ishida
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摘要

采用离子液体[1-乙基-3-甲基咪唑二(三氟甲基磺酰基)亚胺]从表面渗透制备聚偏氟乙烯-三氟乙烯(P(VDFTrFE))凝胶。对制备的P(VD F-TrFE)/IL凝胶进行了结构和电学表征。XRD谱图和FT-IR谱图表明,P(VDF-TrFE)大部分为铁电型Ι晶相形成,但部分P(VDF-TrFE)在P(VDF-TrFE)渗透凝胶中呈现出与ILs复合的新结构。测量了P(VDF-TrFE)/IL渗透凝胶膜的极化开关和压电响应。P(VDF-Tr FE)/IL凝胶膜的压电常数d33增大。
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Structural and Piezoelectric Characterization of P (VDF-TrFE)/Ionic Liquid Gels
Poly(vinylidene fluoride-trifluoroethylene)(P(VDFTrFE)) gels were prepared by the permeating ionic l iquid [1-Ethyl-3-methylimidazolium bis(trifluoromethyl sulfonyl)imide] from the surface. The prepared P(VD F-TrFE)/IL gels were structurally and electrically inv estigated. The XRD patterns and FT-IR spectra impl ied that the most part of the P(VDF-TrFE) formed with the ferroelectric Form Ι crystal phase, however, a part of P(VDF-TrFE) showed the new composited structure with ILs in the P(VDF-TrFE) permeated gels. The polarization switching and piezoelectric res ponse of P(VDF-TrFE)/IL permeated gel films were measured. The piezoelectric constant d33 of P(VDF-Tr FE)/IL gel films increased.
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