低多环芳烃(PAHs)改良鱼烟窑的开发与评价

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摘要

多环芳烃(PAHs)是在吸烟过程中进入食物的致癌污染物。这项研究用于开发一种改进的烟熏窑,并确定其烟熏方法在减少尼日利亚当地消费的鱼的多环芳烃水平方面的影响。对鲶鱼进行了不同方法的熏制。它们是明火熏鱼桶(FOSD)中的木柴,使用改进的熏鱼窑(CISK)的木炭和使用改进的熏鱼窑(GISK)的气体。采用气相色谱(GC) -火焰离子化检测器(FID)法测定多环芳烃。对熏鱼样品中多环芳烃的浓度进行了比较,目的是确定降低鱼样品中多环芳烃浓度的过程。结果表明,FOSD法、CISK法和GISK法的PAHs含量分别为80.01µg/g、20.95µg/g和14.69µg/g。高致癌物苯并(a)芘仅在FOSD中检测到9.20µg/g,而在CISK和GISK中均未检测到。其他多环芳烃均在FOSD中检出,而荧光蒽在所有方法中均异常高,分别为22.08µg/g、10.23µg/g和5.04µg/g。而在改进后的熏鱼窑中,未检出萘、菲、蒽、芘、蒽、苯并(b)芴、苯并(k)芴、苯并(a)芘和苯并(g、h)苝(ND)。所开发的改良鱼熏窑可显著降低多环芳烃含量,值得推荐。
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Development and Evaluation of Low Polycyclic Aromatic Hydrocarbons (PAHs) Improved Fish Smoking Kiln
Polycyclic aromatic hydrocarbons (PAHs) are carcinogenic pollutants which get into foods during smoking. This research was used to develop an improved smoking kiln and to determine its effects of the methods of smoking in reducing the level of PAHs of a locally consumed fish in Nigeria. The fish specie clarias gariepenus (catfish) was smoked with different methods. They are the firewood in open-fire fish smoking drum (FOSD), charcoal using improved fish smoking kiln (CISK) and gas using improved fish smoking kiln (GISK). The PAHs was determined using the Gas Chromatography (GC) coupled with flame ionization detector (FID). Comparison of the concentration of PAHs in smoked fish samples were investigated with the aim of determining the process that has reduced the concentration of the PAHs in the fish samples. The total values of PAHs have shown that the methods FOSD, CISK and GISK have PAHs level of 80.01µg/g, 20.95µg/g and 14.69µg/g respectively. Benzo(a)pyrene, which is highly carcinogenic and posses health risk was found only in FOSD to be 9.20µg/g, while it was not detected in CISK and GISK respectively. As for other PAHs, they were all detected in FOSD, while fluoranthene was exceptionally high in all the methods used as 22.08µg/g, 10.23µg/g and 5.04µg/g respectively. However, naphthalene, phenanthrene, anthracene, pyrene, chrysene, benzo(b)fluoranthrene, benzo(k)fluoranthrene, benzo(a)pyrene and benzo(g,h)perylene were not detected (ND) in the developed improved fish smoking kiln. The developed improved fish smoking kiln has been able to reduce the level of PAHs considerably and is therefore recommended.
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