橄榄核吸附分离废水中镍的研究

A. M. Ahmed, A. Ali, Ahmed Ghazy
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引用次数: 11

摘要

本研究考察了活性炭橄榄石对废水中Ni(II)离子的吸附电位。通过间歇式实验考察了初始浓度、吸附剂用量、搅拌速度、接触时间、温度和溶液pH对吸附过程的影响,并评价了最佳吸附条件。吸附过程符合准二级动力学模型。采用Langmuir吸附等温线模型和freundlichad吸附等温线模型对吸附数据进行分析,发现两者都适用于该吸附过程。计算了正在进行的吸附过程的热力学参数ΔGo、ΔSo和ΔHo,发现吸附过程是吸热的。最后可以看出,活性炭橄榄石对废水中Ni(II)的去除效果优于其他吸附剂。
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Adsorption Separation of Nickel from Wastewater by using Olive Stones
In this study, the adsorption potential of activated carbon olive stone for removal of Ni(II) ions from wastewater has been investigated. The study involves batch type experiments to investigate the effect of initial concentration, adsorbent dose, agitation speed, contact time, temperature and pH of solution on adsorption process and the optimum conditions were evaluated. The adsorption process has fit pseudo-second order kinetic models. Langmuir and Freundlichadsorption isotherm models were applied to analyze adsorption data and both were found to be applicable to this adsorption process. Thermodynamic parameters, e.g., ΔGo, ΔSo and ΔHo of the on-going adsorption process have also been calculated and the sorption process was found to be endothermic. Finally, it can be seen that activated carbon olive stone was found to be more effective for the removal of Ni(II) from waste water than any adsorbent was used.
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