用氢氧化钠蒸汽气化法回收废钽冷凝器中的钽烧结坯

Shigeyuki Katano, Takaaki Wajima, Hideki Nakagome
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引用次数: 30

摘要

从电力设备中使用过的钽电容器中回收钽资源具有重要意义,因为钽的生产一直处于价格和数量不稳定的状态。然而,由于钽电容器中的钽烧结压块被卤化化合物制成的阻燃树脂(模具树脂)强烈地覆盖,因此回收钽烧结压块是困难的。本研究采用氢氧化钠蒸汽气化的方法,通过破坏模具树脂和稳定氢氧化钠中的卤化化合物来回收钽烧结坯,防止卤化气体的排放。用氢氧化钠蒸汽气化法分解模具树脂,回收烧结后的钽。此外,大多数由模具树脂分解产生的卤素气体可以被氢氧化钠捕获,而不会排出卤素气体。上述结果表明,利用氢氧化钠蒸汽气化回收废旧冷凝器中的钽烧结坯有望成为回收电气设备中稀有金属的一种可行方法。
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Recovery of Tantalum Sintered Compact from Used Tantalum Condenser Using Steam Gasification with Sodium Hydroxide

Recovery of tantalum resource from used tantalum capacitor in electric equipment is important because the production of tantalum have not been stable for the price and the quantity. However, recovery of tantalum sintered compact from tantalum capacitor is difficult since the compact strongly covered with the flame retardant resin made of halogenated compounds (mold resin). In this study, steam gasification with sodium hydroxide was applied for recovery of tantalum sintered compact by destroying mold resin and stabilization of halogenated compounds in sodium hydroxide to prevent exhausting halogenated gas. Mold resin can be decomposed by steam gasification with NaOH to recover the sintered compact of tantalum. Furthermore, most halogen gas generated from decomposition of mold resin can be trapped in sodium hydroxide not to exhaust halogen gas. These results suggested that recovery process of tantalum sintered compact from the used condenser using steam gasification with sodium hydroxide is expected as a feasible way to recycle the rare metal in electric equipment.

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Contents Preface Contents Contents Lactic Acid Production from Repeated-Batch and Simultaneous Saccharification and Fermentation of Cassava Starch Wastewater by Amylolytic Lactobacillus Plantarum MSUL 702
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