接触三离子形成缔合常数的理论估计

BioInorganic Reaction Mechanisms Pub Date : 2000-01-01 DOI:10.1515/irm-2000-0402

Willem Η. Mulder, T. Dasgupta, G. Stedman

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引用次数: 4

摘要

摘要从热力学角度出发，推导了接触离子三联体(KIT)形成常数的计算公式。这种方法也产生了离子对的关联常数表达式ΚIP，在相同的近似中，导致对熟悉的Fuoss方程的修改。对过渡金属氰基配合物的K1T公式与文献数据进行了比较。

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Theoretical Estimates of Association Constants for Contact Triple-Ion Formation

Abstract A formula for the calculation of formation constants for ion-triplets in contact, KIT, is derived on the basis of a thermodynamic argument. This approach also yields an expression for the association constants for ion-pairs, ΚIP, within the same approximation, leading to a modification of the familiar Fuoss equation. The formula for K1T is compared with literature data for transition metal cyano complexes.

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BioInorganic Reaction Mechanisms

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