硅化钒化学和电化学稳定性的热力学评价

P. A. Nikolaychuk
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引用次数: 0

摘要

研究了V-Si体系在25℃时的相平衡和化学平衡。估计了Si在bcc-V中25°C时的最大固溶度。计算了饱和溶液中各组分的热力学活度。绘制了V-Si-O体系在25℃时的状态图,并计算了其不变条件的特征。绘制了钒(V)化合物的活度- pH图。绘制了v - si - h2o体系在25℃、气压为1 bar、溶液中离子活度为1 mol/L时的电位- pH图。对V-Si系合金的化学稳定性和电化学稳定性进行了热力学分析。
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Thermodynamic Assessment of Chemical and Electrochemical Stability of Vanadium Silicides
The phase and chemical equilibria in the V–Si system at 25 °C were considered. The possible maximum solid solubility of Si in bcc-V at 25 °C was estimated. The thermodynamic activities of the components in this saturated solution were calculated. The state diagram of the V–Si–O system at 25 °C was plotted and the characteristics of their invariant conditions were calculated. The activity – pH diagram for vanadium(V) compounds was plotted. The potential – pH diagram of the V–Si–H 2 O system at 25 °C, air pressure of 1 bar, and activities of ions in solution equal to 1 mol/L was plotted. The thermodynamic analysis of chemical and electrochemical stability of the V–Si system alloys was performed.
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0.70
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审稿时长
17 weeks
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