挥发性裂变产物在FLiNaK盐中的蒸发行为

Masami Taira, Y. Arita, M. Yamawaki
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引用次数: 10

摘要

熔盐堆(MSR)是第四代核电站规划的概念之一,但对熔盐堆发生的严重事故的研究很少。在MSR发生的严重事故中,熔盐和燃料将暴露在空气中,一些裂变产物将释放到环境中。将熔融的FLiNaK盐(LiF-NaF-KF: 46.5-11.5-42 mol%)与CsI(FLiNaK- CsI: 99-1 mol%)蒸发,用质谱法测定释放气体。上述样品的蒸发气体主要为CsI和KI。在相同温度下,CsI的蒸气压值约为纯CsI蒸气压的1 ~ 2次方的10倍。因此,预计FLiNaK会阻止CsI的释放。另一方面,尽管KI未包含在原始样品中,但KI释放明显。
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The Evaporation Behavior of Volatile Fission Products in FLiNaK Salt
Molten salt reactor (MSR) was suggested for the one of the nuclear power plant concepts planned for generation IV. However, little study had been done on the severe accident at MSR. The one of the severe accident at MSR is considered that the molten salt with fuel will be exposed to air and some fission products will release to environment. The molten FLiNaK salt (LiF-NaF-KF: 46.5–11.5-42 mol%) with CsI(FLiNaK- CsI: 99-1 mol%) was evaporated and released gases were measured by mass spectrometry. The evaporated gases from above sample were mainly CsI and KI. The value of vapor pressure for CsI was low about ten to the first ∼ second power of vapor pressure for pure CsI at same temperature. Therefore, it is expected that FLiNaK prevents the release of CsI. On the other hand, despite KI were not included in original sample, KI released significantly.
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