氧化铝催化生产二甲醚的管状固定床反应器的建模

K. Dagde, Uduak Sylvanus Harry
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引用次数: 1

摘要

建立了氧化铝催化生产二甲醚的绝热管式固定床反应器的行为预测模型。稳态模型将文献中得到的反应速率动力学表达式纳入模型方程。采用四阶龙格-库塔法结合计算机模拟器(MATLAB 7.7代码)对模型进行数值积分。在相同操作条件下,将模型预测结果与文献中获得的数据进行比较,得到了很好的一致性,变化范围为0.5%至2.7%。模拟结果表明,温度和进料流量等参数对二甲醚的产率影响较大,在557 ~ 570K的催化剂床高为2 ~ 4m时二甲醚产率最佳。
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Modeling of a Tubular Fixed-Bed Reactor for the Production of Dimethyl Ether Using Alumina Catalyst
A model to predict the behavior of an adiabatic tubular fixed-bed reactor for the production of dimethyl ether using alumina catalyst was developed. The steady state model incorporates the reaction rate kinetic expression obtained from literature into the model equations. The models were integrated numerically using Fourth-order Runge-Kutta method incorporated into a computer simulator (MATLAB 7.7 code). Model predictions are compared with data obtained from the literature under the same operating conditions and a good agreement is obtained with a variation ranging from 0.5% to 2.7%. The simulation results show that the production of dimethyl ether is greatly affected by parameters such as temperature, and feed flow rate with optimum yield of DME at a catalyst bed height of 2-4m at a temperature of 557 to 570K.
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