Beth Rather , Brian Moulton , Michael J. Zaworotko , Florent Perret , Nicole Morel-Desrosiers , Eric Da Silva , Anthony W. Coleman
{"title":"杯芳烃二聚体嵌入由二胺基质形成的疏水腔中的晶体工程","authors":"Beth Rather , Brian Moulton , Michael J. Zaworotko , Florent Perret , Nicole Morel-Desrosiers , Eric Da Silva , Anthony W. Coleman","doi":"10.1016/S1463-0184(03)00047-9","DOIUrl":null,"url":null,"abstract":"<div><p>The crystal structure of the 2:1 1,6-diamino-hexane: <em>para</em>-H-calix-4-arene-25,27-di-phosphonate complex shows a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules, the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule is compensated by chain folding in the diamine</p></div>","PeriodicalId":10766,"journal":{"name":"Crystal Engineering","volume":"6 1","pages":"Pages 15-21"},"PeriodicalIF":0.0000,"publicationDate":"2003-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1463-0184(03)00047-9","citationCount":"14","resultStr":"{\"title\":\"Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix\",\"authors\":\"Beth Rather , Brian Moulton , Michael J. Zaworotko , Florent Perret , Nicole Morel-Desrosiers , Eric Da Silva , Anthony W. Coleman\",\"doi\":\"10.1016/S1463-0184(03)00047-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The crystal structure of the 2:1 1,6-diamino-hexane: <em>para</em>-H-calix-4-arene-25,27-di-phosphonate complex shows a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules, the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule is compensated by chain folding in the diamine</p></div>\",\"PeriodicalId\":10766,\"journal\":{\"name\":\"Crystal Engineering\",\"volume\":\"6 1\",\"pages\":\"Pages 15-21\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2003-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1463-0184(03)00047-9\",\"citationCount\":\"14\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1463018403000479\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1463018403000479","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix
The crystal structure of the 2:1 1,6-diamino-hexane: para-H-calix-4-arene-25,27-di-phosphonate complex shows a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules, the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule is compensated by chain folding in the diamine