含TeI3 -配体的三角形簇碎片[Mo3(µ3- te)(µ2-Te2)3]4+的合成与结构

V. Fedin, H. Imoto, Taro Saito
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引用次数: 17

摘要

钼、碲和碘的高温反应生成Mo3Te10I10, Mo3Te10I10含有三角形簇片[Mo3(µ2-Te)(µ2-Te2)3]4+和三个Tel3 -配体。
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Synthesis and structure of Mo3Te10I10 containing TeI3– ligands coordinated to a triangular cluster fragment [Mo3(µ3-Te)(µ2-Te2)3]4+
High-temperature reaction of molybdenum, tellurium and iodine produces Mo3Te10I10, which contains triangular cluster fragment [Mo3(µ2-Te)(µ2-Te2)3]4+ and three Tel3– ligands.
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