天然和化学原料催化废食用油酯交换反应的研究

Marwa F. Abdul Jabbar, Abdulkareem Dahash Affat, Luay Badr Hamad
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摘要

由于化石燃料使用增加的温室效应,导致化石燃料可用的时间增加。由于生物柴油对环境的好处和其可再生资源的生产,生物柴油越来越受欢迎。由于二手食用油供应充足,人们对生产生物柴油的兴趣正在上升。本研究考察了CaO和锯末作为多相催化剂在用废食用油进行乙醇酯交换制生物柴油中的作用。考察了后续变量对生物柴油产率的影响。这些参数包括催化剂浓度(0.5- 3wt %)、反应时间(1-4小时)、乙醇与油的摩尔比(8:1 - 20:1)和温度(45 ~ 80℃)。结果表明,与木屑催化剂相比,CaO催化剂效率更高,在催化剂条件(0.50%)、乙醇油摩尔比为20:1、65摄氏度温度下,CaO催化剂的最大收率为75%,CaO催化剂的最大收率为95%。结果表明,本研究开发的催化剂生产的生物柴油燃料在生物柴油燃料的可接受范围内。
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Transesterification of Waste Cooking Oil Using Natural and Chemical Materials as Catalyst
Due to the greenhouse effect of increased fossil fuel use, resulting in an increase in the period during which fossil fuels will remain available. Because of its advantages for the environment and its production from renewable resources, biodiesel has grown more appealing. As there is a supply of used cooking oil, interest in producing biodiesel is rising. This research examines how CaO and sawdust function as heterogeneous catalysts in transesterification regarding ethanol to produce bio-diesel from the used cooking oil. The impacts of the subsequent variables on the yield of the created biodiesel were investigated. Those parameters include the catalyst concentration (0.5-3 wt%), reaction period (1-4 hr), the molar ratio of ethanol to oil (8:1– 20:1), and temperature (45 to 80 °C). This led to the discovery that CaO catalyst is more efficient compared to the sawdust catalyst, with the maximum percentage yield being 75% for the sawdust catalyst and 95% for the CaO catalyst under catalyst conditions (0.50%), ethanol oil molar ratio of 20:1, and 65 Celsius temperature for 3 hours. It was evident from the results that the biodiesel fuel produced by the catalyst developed in this study fell within the acceptable range of biodiesel fuel.
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