Ho-=SUP -3+ /SUP=- SrY- 2 = =SUB -O- 4 =- SUB

Сергей Иванович Никитин, Е.М. Куташова, Р. В. Юсупов, Р.Г. Батулин, А. Г. Киямов, Иван Энверович Мумджи, Б. З. Малкин
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摘要

本文报道了用位置选择激光光谱法对SrY2O4单晶中杂质Ho3+中心的发射和激发光谱进行了详细的研究。利用实测光谱构造了在Y1和Y2两个结构不等效位置上取代Y3+的Ho3+离子的5I8、5I7、5I6、5S2和5F4多重态具有局域Cs对称的能级图。这些能量方案在晶体场理论的框架中得到了很好的描述,并在Y1和Y2两个位置确定了Ho3+离子的15个晶体场参数集。计算得到的EPR谱参数与先前发表的实验数据一致。
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Селективная лазерная спектроскопия примесных центров ионов Ho-=SUP=-3+-=/SUP=- в кристалле SrY-=SUB=-2-=/SUB=-O-=SUB=-4-=/SUB=-
Detailed studies of emission and excitation spectra of impurity Ho3+ centers in the SrY2O4 single crystal performed by means of the site-selective laser spectroscopy are reported. The energy levels patterns for the 5I8, 5I7, 5I6, 5S2 and 5F4 multiplets of Ho3+ ions which substitute for the Y3+ ions at the two structurally nonequivalent sites Y1 and Y2 with the local Cs symmetry are constructed by making use of the measured spectra. These energy schemes are well described in the framework of the crystal field theory, the sets of 15 crystal field parameters are determined for Ho3+ ions at both Y1 and Y2 sites. The calculated parameters of the EPR spectra agree with the earlier published experimental data.
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