新型流动砂固化剂的合成

A. Sharipova, I.L. Akhmadjоnov, A.B. Аbdikamalova, K. Akbarov, S. Kuldasheva
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引用次数: 0

摘要

水溶性聚合物制剂的合成问题,可在农业中作为土壤和流动沙的结构形成剂,以防止水,风,机械侵蚀,增加肥力,吸湿,保湿,固结土壤,垃圾场和流动沙,以消除对环境的负面影响。以顺丁酸和丙烯酰胺为共聚单体,过硫酸钾为引发剂。结果表明,当引发剂的浓度从0.01增加到0.05%(单体重量)时,促进了聚合过程的速度增加,并在更长的时间内保持其值,将该过程的时间从7.0-6.5小时减少到5.5 -6小时。在这种情况下,当原料配比为1:5时,聚合反应的产率正好从81.2%提高到96.0%。当在反应混合物中加入少量碱时,可以得到高分子量的聚合物。在这种情况下,该工艺的产率提高,反应时间减少2-3小时。利用合成试剂和其他各种试剂对固定过程进行动力学分析,以及对砂土塑性强度的变化进行分析,结果表明,在重力或毛细力的影响下,固定剂的渗透条件与空间中自由流动的形成与粘合剂的类型和砂土本身的组成有关。
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Synthesis of New Fixings of Mobile Sands
The issues of the synthesis of a water-soluble polymer preparation, which can find application in agriculture as a structure-forming agent of soils and mobile sands to prevent water, wind, mechanical erosion, increase fertility, moisture absorption, moisture retention, consolidation of soils, dumps, and mobile sands to eliminate negative effects on the environment. Maleic acid and acrylamide were chosen as monomers for the copolymerization reaction, and potassium persulfate was chosen as the initiator. As it turned out, an increase in the concentration of the initiator from 0.01 to 0.05% (by weight of monomers) promotes an increase in the rate of the polymerization process, maintaining its value for a longer time, reducing the time of this process from 7.0-6.5 to 5, 5-6 hours. In this case, the yield of the polymerization reaction increased exactly from 81.2 to 96.0% for the reaction with the ratio of starting materials 1: 5. When a small amount of alkali is introduced into the reaction mixture, high molecular weight polymers can be obtained. In this case, the yield of the process increases, and the reaction time is reduced by 2-3 hours. Analysis of the kinetics of fixing processes using synthesized and various other reagents, as well as changes in the plastic strength of sands, showed the dependence of the conditions of penetration of the fixer with the formation of a free flow in space under the influence of gravitational or capillary forces on the type of binding agent and on the composition of the sand itself.
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来源期刊
Alinteri Journal of Agriculture Sciences
Alinteri Journal of Agriculture Sciences AGRICULTURE, MULTIDISCIPLINARY-
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