源自红树林的内生真菌Coriolopsis sp. [j]

Liang-Liang Chen, Pei-Pei Wang, Huiqin Chen, Zhi-kai Guo, Hao Wang, Haofu Dai, Wenli Mei
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引用次数: 13

摘要

6个新的呋喃衍生物,命名为5-(3-甲氧基-3-氧丙基)-呋喃-2-羧酸(1)、1-(5-(2-羟基丙基)-呋喃-2-基)-戊烷-3-酮(2)、2-羟基-1-(5-(1,2-二羟丙基)-呋喃-2-基)-戊烷-1-酮(3)、1-(5-(1,2-二羟丙基)-呋喃-2-基)-戊烷-1-酮(4)、5-(1-羟基-4-烯-1-基)-呋喃-2-羧酸(5)和5-(3-羟基戊基)-呋喃-2-羧酸(6),以及两种新的天然产物。5-(1-羟基戊基)-呋喃-2-羧酸(7)和(E)-5-(2-羧乙烯基)-呋喃-2-羧酸(8)分别从内生真菌Coriolopsis sp. J5的固体大米发酵中分离得到,该真菌来源于红树林植物Ceriops tagal。它们的结构是基于一维和二维核磁共振波谱、hresms测量以及与文献的比较而明确地阐明的。
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New Furan Derivatives from a Mangrove-Derived Endophytic Fungus Coriolopsis sp. J5
Six new furan derivatives, named 5-(3-methoxy-3-oxopropyl)-furan-2-carboxylic acid (1), 1-(5-(2-hydroxypropanoyl)-furan-2-yl)-pentan-3-one (2), 2-hydroxy-1-(5-(1-hydroxypentyl)-furan-2-yl)-propan-1-one (3), 1-(5-(1,2-dihydroxypropyl)-furan-2-yl)-pentan-1-one (4), 5-(1-hydroxypent-4-en-1-yl)-furan-2-carboxylic acid (5) and 5-(3-hydroxypentyl)-furan-2-carboxylic acid (6), together with two new natural products, named 5-(1-hydroxypentyl)-furan-2-carboxylic acid (7) and (E)-5-(2-carboxyvinyl)-furan-2-carboxylic acid (8), were isolated from the solid rice fermentation of endophytic fungus Coriolopsis sp. J5, which was derived from mangrove plant Ceriops tagal. Their structures were unambiguously elucidated based on 1D and 2D NMR spectroscopy, and by HRESIMS measurements, as well as by comparison with the literature.
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