新型脏油泥破乳剂的制备及应用

Li Wu, Lihua Li, Yinglu Yang, Cong Sheng, Xian Wu
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引用次数: 0

摘要

本研究采用乳液共聚法制备破乳剂DW1。采用红外光谱(FT-IR)、凝胶渗透色谱(GPC)、核磁共振(1H-NMR)、核磁共振(13C-NMR)和粒度分析对破乳剂DW1进行了表征。以新疆污泥为目标处理对象,以DW1为破乳体系进行破乳实验,并对处理前后的污泥进行扫描电镜分析。结果表明,合成的破乳剂DW1的质量-平均分子量(Mw)为454319 ~ 1388086,数-平均分子量(Mn)为801880,分子量分布指数为1.73104,D50为26.00µm,平均粒径为25.00µm,粒径分布不均匀,稳定性好。破乳实验表明,DW1在新疆某油田的除油率可达99.55%。
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Preparation and Application of New Demulsifier for Dirty Oil Sludge
In this study, a demulsifier DW1 was prepared by emulsion copolymerization.The demulsifier DW1 was characterized by FT-IR spectroscopy, gel permeation chromatography (GPC), 1H-NMR, 13C-NMR and particle size analysis.The demulsification experiment using DW1 as demulsification system was carried out with Xinjiang sludge as the target treatment object, and the sludge before and after treatment was analyzed by Scanning electron microscopy.The results showed that the synthetic demulsifier DW1 had weight-average molecular weights (Mw) of rang from 454319 to 1388086 and number-average molecular weights (Mn) of 801880, molecular weight distribution index of 1.73104, D50 of 26.00 µm, average particle size of 25.00 µm, non-uniform particle size distribution, and good stability of DW1.The demulsification experiment shows that the oil removal rate of DW1 on a Xinjiang oil field can reach 99.55%.
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