{"title":"高价碘化合物的光化学","authors":"Kunfang Jia, Yiyun Chen","doi":"10.1002/9780470682531.pat0958","DOIUrl":null,"url":null,"abstract":"I. HYPERVALENT IODINE COMPOUNDS IN PHOTOCHEMISTRY . . . . . . . . 2 A. Direct Photoexcitation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 B. Indirect Photosensitization (Photoredox Catalysis) . . . . . . . . . . . . . . . . . . 2 II. HYPERVALENT IODINE COMPOUNDS FOR SUBSTRATE ACTIVATION IN PHOTOCHEMISTRY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 A. Carboxylic Acid Activation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1. Direct irradiation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2. Photoredox catalysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 B. Alcohol Activation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 1. Direct irradiation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 2. Photoredox catalysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 C. Amine Activation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 1. Direct irradiation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 III. HYPERVALENT IODINE COMPOUNDS AS REAGENTS IN PHOTOCHEMISTRY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 A. Diaryl Iodonium Salts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 B. Trifluoromethyl Benziodoxoles (Togni Reagent) . . . . . . . . . . . . . . . . . . . . 28 C. Azido Benziodoxoles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 D. Hydroxyl/acetoxyl/alkoxyl Benziodoxoles . . . . . . . . . . . . . . . . . . . . . . . 30 E. Alkynyl Benziodoxoles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 F. Cyano Benziodoxoles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 IV. CONCLUSION AND OUTLOOK . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 V. REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39","PeriodicalId":20036,"journal":{"name":"Patai's Chemistry of Functional Groups","volume":"39 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2018-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Photochemistry of Hypervalent Iodine Compounds\",\"authors\":\"Kunfang Jia, Yiyun Chen\",\"doi\":\"10.1002/9780470682531.pat0958\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"I. HYPERVALENT IODINE COMPOUNDS IN PHOTOCHEMISTRY . . . . . . . . 2 A. Direct Photoexcitation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 B. Indirect Photosensitization (Photoredox Catalysis) . . . . . . . . . . . . . . . . . . 2 II. HYPERVALENT IODINE COMPOUNDS FOR SUBSTRATE ACTIVATION IN PHOTOCHEMISTRY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 A. Carboxylic Acid Activation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1. Direct irradiation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2. Photoredox catalysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 B. Alcohol Activation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 1. Direct irradiation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 2. Photoredox catalysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 C. Amine Activation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 1. Direct irradiation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 III. HYPERVALENT IODINE COMPOUNDS AS REAGENTS IN PHOTOCHEMISTRY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 A. Diaryl Iodonium Salts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 B. Trifluoromethyl Benziodoxoles (Togni Reagent) . . . . . . . . . . . . . . . . . . . . 28 C. Azido Benziodoxoles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 D. Hydroxyl/acetoxyl/alkoxyl Benziodoxoles . . . . . . . . . . . . . . . . . . . . . . . 30 E. Alkynyl Benziodoxoles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 F. Cyano Benziodoxoles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 IV. CONCLUSION AND OUTLOOK . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 V. REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39\",\"PeriodicalId\":20036,\"journal\":{\"name\":\"Patai's Chemistry of Functional Groups\",\"volume\":\"39 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-06-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Patai's Chemistry of Functional Groups\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/9780470682531.pat0958\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Patai's Chemistry of Functional Groups","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780470682531.pat0958","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
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