丙烯酸含量对改性NypaFruticans再生纤维素生物复合膜的影响

G. Vaniespree, H. Salmah, P.L. Teh, M. Marliza
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摘要

番荔枝(Nypafruticans, NF)是一种农业作物,在马来西亚大量生长。它可以作为商品纤维素的替代品,以利用生物质废弃物。以NF和微晶纤维素(MCC)为原料,用氯化锂(LiCl)和N, N-二甲基乙酰胺(DMAc)溶解纤维素,制备了再生纤维素(RC)生物复合膜。采用丙烯酸(AA)作为NF的表面改性剂。结果表明,在RC生物复合膜中加入NF可使RC生物复合膜的拉伸强度和杨氏模量提高3 wt%。RC生物复合膜的断裂伸长率随NF含量的增加而降低。添加AA的改性NF提高了RC生物复合膜的拉伸强度和杨氏模量,但降低了断裂伸长率。当AA含量为3%时,RC生物复合膜的拉伸强度和杨氏模量最高。
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Effect of Acrylic Acid Content on Modified NypaFruticans Regenerated Cellulose Biocomposite Films

Nypafruticans (NF) is one of the agriculture crops, which grows abundantly in Malaysia. It can be used as asubstitute for commercial cellulose in order to utilize biomass waste. Regenerated cellulose (RC) biocomposite films from NF and microcrystalline cellulose (MCC) were prepared by dissolving cellulose in lithium chloride (LiCl) and N, N-dimethylacetamide (DMAc). Acrylic acid (AA) was used as surface modifier of NF. The results indicated that the addition of NF in RC biocomposite films increases the tensile strength and Young's modulus of RC biocomposite film up to 3 wt%. The elongation at break of RC biocomposite films decreased with increases of NF content. The modified NF with AA improved the tensile strength and Young's modulus but reduced the elongation at break of RC biocomposite films. The highest tensile strength and Young's modulus of RC biocomposite films was exhibited by 3% AA content.

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