克鲁克斯涨落定理中的缺陷

Gokaran Shukla
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引用次数: 0

摘要

克鲁克斯涨落定理的存在(即使在微观层面,在很短的时间内)是对热力学第二定律的直接威胁。在本文中,我们将强调克鲁克斯涨落定理假设中存在的缺陷,因此,我们将确认热力学第二定律在任何温度、压力和任何尺度(时间、长度尺度)下的有效性。我们将验证Loschmidts悖论,并将证明在自然界中任何非零的有限温度(T>0 K)和压力(P>0)下,没有物理方向过程可以完全可逆。
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Flaw in Crooks Fluctuation Theorem
The existence of Crooks fluctuation theorem (even at microscopic level, in a very short time period) is a direct threat to the second law of thermodynamics. In this paper, we will underline the flaw that exists in Crooks fluctuation theorem assumptions, and thus, we will confirm the validity of the second law of thermodynamics at any temperature, pressure, and at any scale (time, and length-scale) in nature. We will validate the Loschmidts paradox, and will show that no physical directional-process can be perfectly-reversible at any non-zero, finite temperature (T>0 K) and pressure (P>0) in nature.
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