基于任务型离子液体的超辅助分散离子液-液微萃取快速分析水和废水样品中的铬(III, VI)

V. Saheb, T. Shamspur
{"title":"基于任务型离子液体的超辅助分散离子液-液微萃取快速分析水和废水样品中的铬(III, VI)","authors":"V. Saheb, T. Shamspur","doi":"10.24200/amecj.v5.i01.170","DOIUrl":null,"url":null,"abstract":" In this research, 2-mercapto-1-methylimidazole a novel Task-specific ionic liquid (C4H6N2S; HS-CH3-IM) was used with a new approach for speciation of Cr (III, VI) from water samples by ultra-assisted dispersive ionic liquid-liquid microextraction procedure (USA-D-ILLME). Due to the procedure, 100 mg of HS-CH3-IM and 0.2 mL of acetone were mixed and injected into 10 mL of water or standard Cr (III) and Cr (VI) solution in the conical tube. After stirring for 5 min, the Cr (VI) and Cr (III) were extracted with a positive and negative charge of the thiol group (HS2+, HS-) in pH 2 or 8 and pH 5, respectively. The  Cr (III, VI) loaded on the HS-CH3-IM was back-extracted in a liquid solution. Finally, the concentration of the Cr (III, VI) ions in a remained solution were measured with ET-AAS . The total chromium was determined in water samples by summarizing the Cr (VI) and Cr (III) contents. All parameters such as the amount of HS-CH3-IM, the sample volume, pH, and the shaking/centrifuging time were optimized. Under the optimal conditions, good linear range (LR), LOD, and enrichment factor (EF) were obtained 0.05–1.7 μg L−1, 15 ng L−1, and 19.82 respectively (RSD% < 1.45). ","PeriodicalId":7797,"journal":{"name":"Analytical Methods in Environmental Chemistry Journal","volume":"44 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Rapid analysis of chromium (III, VI) in water and wastewater samples based on Task-specific ionic liquid by the ultra-assisted dispersive ionic liquid-liquid microextraction\",\"authors\":\"V. Saheb, T. Shamspur\",\"doi\":\"10.24200/amecj.v5.i01.170\",\"DOIUrl\":null,\"url\":null,\"abstract\":\" In this research, 2-mercapto-1-methylimidazole a novel Task-specific ionic liquid (C4H6N2S; HS-CH3-IM) was used with a new approach for speciation of Cr (III, VI) from water samples by ultra-assisted dispersive ionic liquid-liquid microextraction procedure (USA-D-ILLME). Due to the procedure, 100 mg of HS-CH3-IM and 0.2 mL of acetone were mixed and injected into 10 mL of water or standard Cr (III) and Cr (VI) solution in the conical tube. After stirring for 5 min, the Cr (VI) and Cr (III) were extracted with a positive and negative charge of the thiol group (HS2+, HS-) in pH 2 or 8 and pH 5, respectively. The  Cr (III, VI) loaded on the HS-CH3-IM was back-extracted in a liquid solution. Finally, the concentration of the Cr (III, VI) ions in a remained solution were measured with ET-AAS . The total chromium was determined in water samples by summarizing the Cr (VI) and Cr (III) contents. All parameters such as the amount of HS-CH3-IM, the sample volume, pH, and the shaking/centrifuging time were optimized. Under the optimal conditions, good linear range (LR), LOD, and enrichment factor (EF) were obtained 0.05–1.7 μg L−1, 15 ng L−1, and 19.82 respectively (RSD% < 1.45). \",\"PeriodicalId\":7797,\"journal\":{\"name\":\"Analytical Methods in Environmental Chemistry Journal\",\"volume\":\"44 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-03-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Methods in Environmental Chemistry Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.24200/amecj.v5.i01.170\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Methods in Environmental Chemistry Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.24200/amecj.v5.i01.170","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1

摘要

在本研究中,2-巯基-1-甲基咪唑是一种新型的任务特异性离子液体(C4H6N2S;采用超辅助分散离子液-液微萃取法(USA-D-ILLME),采用HS-CH3-IM对水样中Cr (III, VI)进行了形态分析。在此过程中,将HS-CH3-IM 100 mg与0.2 mL丙酮混合后,在锥形管中注入10 mL水或标准Cr (III)和Cr (VI)溶液。搅拌5min后,分别在pH 2或8和pH 5中提取带正、负电荷的硫醇基团(HS2+、HS-)的Cr (VI)和Cr (III)。负载在HS-CH3-IM上的Cr (III, VI)在液体溶液中反提。最后用ET-AAS法测定剩余溶液中Cr (III, VI)离子的浓度。通过对水样中Cr (VI)和Cr (III)含量的汇总,确定了水样中总铬的含量。对HS-CH3-IM投加量、样品体积、pH、振荡/离心时间等参数进行优化。在此条件下,样品的线性范围为0.05 ~ 1.7 μg L−1,LOD为15 ng L−1,富集因子为19.82 (RSD% < 1.45)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Rapid analysis of chromium (III, VI) in water and wastewater samples based on Task-specific ionic liquid by the ultra-assisted dispersive ionic liquid-liquid microextraction
 In this research, 2-mercapto-1-methylimidazole a novel Task-specific ionic liquid (C4H6N2S; HS-CH3-IM) was used with a new approach for speciation of Cr (III, VI) from water samples by ultra-assisted dispersive ionic liquid-liquid microextraction procedure (USA-D-ILLME). Due to the procedure, 100 mg of HS-CH3-IM and 0.2 mL of acetone were mixed and injected into 10 mL of water or standard Cr (III) and Cr (VI) solution in the conical tube. After stirring for 5 min, the Cr (VI) and Cr (III) were extracted with a positive and negative charge of the thiol group (HS2+, HS-) in pH 2 or 8 and pH 5, respectively. The  Cr (III, VI) loaded on the HS-CH3-IM was back-extracted in a liquid solution. Finally, the concentration of the Cr (III, VI) ions in a remained solution were measured with ET-AAS . The total chromium was determined in water samples by summarizing the Cr (VI) and Cr (III) contents. All parameters such as the amount of HS-CH3-IM, the sample volume, pH, and the shaking/centrifuging time were optimized. Under the optimal conditions, good linear range (LR), LOD, and enrichment factor (EF) were obtained 0.05–1.7 μg L−1, 15 ng L−1, and 19.82 respectively (RSD% < 1.45). 
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.10
自引率
0.00%
发文量
0
期刊最新文献
Determine methylene blue based on carbon paste electrode modified with nanoparticles of nickel oxide-nitrogen carbon quantum dots and carbon structures by cyclic voltammetry A review: Exploratory analysis of recent advancement in green analytical chemistry application the Determination and evaluation of trace elements in the blood of radiography workers using graphite furnace atomic absorption spectrometry Chromium desalinization using novel chitosan functionalized iron oxide- biochar composites: Analysis, synthesis, characterization and adsorption performance Solid phase-fabrication of multi-walled carbon nanotubes and their derivatives for efficient extraction and analysis of Bismarck Brown-Y Dye from aqueous solution
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1