用桉树叶制备氧化锌纳米颗粒去除酸性黑210染料的绿色制备和表征

Zahraa A. Najm, A. M. Shakorfow, Najah Al Mhanna, Ahmed K. Hassan, Mohammed A. Atyia
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摘要

本研究以硫酸锌为原料,采用一种环保、低成本的合成方法制备氧化锌纳米颗粒。桉叶提取物是合成ZnO纳米粒子的有效螯合封盖剂。利用FT-IR、FE-SEM、EDAX、AFM和Zeta电位分析研究了ZnO纳米颗粒的结构、形貌、热行为、化学成分和光学性质。FE-SEM图像证实,ZnO纳米粒子为晶体和球形,粒径范围为(22 ~ 37)nm。采用两种方法制备ZnO纳米粒子。第一种方法需要煅烧得到的ZnO纳米粒子,而第二种方法则不需要。将制备的ZnO纳米粒子作为吸附剂用于去除模拟废水中的酸性黑210染料(AB210)。焙烧和未焙烧ZnO纳米粒子的去除率分别为57%和59%。
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Green Fabrication and Characterization of Zinc Oxide Nanoparticles using Eucalyptus Leaves for Removing Acid Black 210 Dye from an Aqueous Medium
This study uses an environmentally friendly and low-cost synthesis method to manufacture zinc oxide nanoparticles (ZnO NPs) by using zinc sulfate. Eucalyptus leaf extract is an effective chelating and capping agent for synthesizing ZnO NPs. The structure, morphology, thermal behavior, chemical composition, and optical properties of ZnO nanoparticles were studied utilizing FT-IR, FE-SEM, EDAX, AFM, and Zeta potential analysis. The FE-SEM pictures confirmed that the ZnO NPs with a size range of (22-37) nm were crystalline and spherical. Two methods were used to prepare ZnO NPs. The first method involved calcining the resulting ZnO NPs, while the second method did not. The prepared ZnO NPs were used as adsorbents for removing acid black 210 dye (AB210) from simulated wastewater. The removal efficiency using calcinated and uncalcinated ZnO NPs was 57 % and 59 %, respectively.
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