磁场对酸性介质中低碳钢腐蚀的抑制作用

Obi Tamadu, Mejeha Maurice, Okeoma Bierechi
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引用次数: 0

摘要

用重量法研究了室温下外加磁场对低碳钢在1.0M HCl和0.5M H2SO4溶液中的缓蚀作用。一个本地制造的具有可变输出的电磁铁,由直流电源电压供电,提供磁场。在一个典型的实验中,将外加磁场垂直施加在完全浸入选定的酸溶液中的低碳钢片表面,曝光时间为两小时。结果表明,在1.0M HCl和0.5M H2SO4溶液中,低碳钢的腐蚀速率随外加磁场的增大而减小。这表明外加磁场的存在抑制了低碳钢在测试溶液中的腐蚀。结果还表明,磁场的保护效率随着外加磁场的增大而增大。当磁场强度从118.2 ~ 764.3mG[或0.01182 ~ 0.07643 mT]增加时,低碳钢在1.0M HCl酸溶液中的保护效率从36.34 ~ 62.67%提高,在0.5M H2SO4酸溶液中的保护效率从12.68 ~ 46.88%提高。结果表明,磁场的抑制作用部分归因于横向磁阻现象,部分归因于磁场对电化学体系中组成离子的质量输运性质的影响
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The inhibitive effect of magnetic fields on mild steel corrosion in acidic media
The inhibitive effect of applied magnetic fields on the corrosion of mild steel in 1.0M HCl and 0.5M H2SO4 acid solutions has been investigated at room temperature by using the gravimetric technique. A locally made electromagnet with variable outputs and powered by a direct current source voltage provided the magnetic fields. In a typical experiment, the applied magnetic field was applied perpendicularly onto the surface of a mild steel coupon immersed completely in a chosen acid solution for an exposure time of two hours. It was observed that the corrosion rates of mild steel determined for each case of 1.0M HCl and 0.5M H2SO4 test solutions decrease as the applied magnetic field increases. This indicates that the presence of the applied magnetic field inhibits the corrosion of the mild steel in the test solutions. Results also show that the protection efficiency of the magnetic field increases as the applied magnetic field increases. More specifically, as the magnetic field was increased from 118.2 - 764.3mG [or 0.01182 - 0.07643 mT], the protection efficiency increased from 36.34 - 62.67% for mild steel in 1.0M HCl acid solution, while for mild steel in 0.5M H2SO4 acid solution, the protection efficiency increased from 12.68 - 46.88%. It was demonstrated that the observed inhibitive effect of the magnetic fields can be attributed partly to the phenomenon of transverse magnetoresistance and partly to the effect of the magnetic fields on the mass transport properties of the constituent ions in the electrochemical system
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Zastita materijala
Zastita materijala Materials Science-General Materials Science
CiteScore
0.80
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0.00%
发文量
26
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