吸湿对玻璃纤维增强复合材料拉伸和弯曲性能的影响

R. Prakash, V. Viswanath
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摘要

近年来,由于玻璃纤维增强塑料(GFRP)在腐蚀性环境中的耐久性和化学稳定性优于金属,因此在水下应用中的使用越来越多。然而,水分渗透到聚合物基体中会对复合材料的机械性能产生不利影响。本研究分析了清水和模拟海水(3.5% NaCl盐)对GFRP试件力学性能的影响。对不同含水率的复合材料试样进行拉伸试验和三点弯曲试验,表征复合材料的吸湿力学退化。对试样进行了重量试验,计算了吸湿参数。结果表明,与咸水相比,白水的吸收速度更快。利用这些参数,利用商业有限元软件ABAQUS®建立了瞬态水分扩散模型。拉伸和三点弯曲试验结果表明,玻璃纤维增强环氧树脂复合材料的拉伸和弯曲性能随着普通水和盐水的暴露而下降。在ABAQUS中建立了水-力耦合模型,并将仿真结果与实际试验结果进行了比较。采用扫描电子显微镜对失效试样的断口表面进行了观察。机械降解的原因似乎是由于水分子的渗透导致纤维-基质界面的恶化。
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Effect of Moisture Absorption on the Tensile and Flexural Properties of Glass Fiber Reinforced Composite Materials
The use of Glass fiber reinforced plastics (GFRP) in underwater applications has been increasing in recent times, due to its superior durability and chemical stability in corrosive environments compared to metals. However, penetration of moisture in to the polymer matrix can adversely affect the mechanical properties of composite materials. In this study, the effect of exposure to plain water and simulated sea water (3.5% by weight NaCl salt) water on the mechanical properties of GFRP specimens has been analyzed. Tensile and three point bend tests were conducted on composite specimens with different moisture contents to characterize the mechanical degradation due to moisture absorption. Gravimetric tests were conducted on specimens to calculate the moisture absorption parameters. The results indicate that plain water is absorbed at a faster rate compared to salt water. Using these parameters, a transient moisture diffusion model was developed using commercial finite element software ABAQUS®. The results of tensile and three point bend testing indicate that both tensile and flexural properties of glass fiber reinforced epoxy composites degrade with exposure to plain water and salt water. Further, a coupled hygro-mechanical model was developed in ABAQUS® and the simulation results were compared with actual test results. Scanning electron Microscopy was used to examine the fracture surface of failed specimens. The cause for mechanical degradation seems to be the deterioration of fiber-matrix interface due to the penetration of water molecules.
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