金属和类金属的烷氧化物和烷基烷氧化物

R.C Mehrotra
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引用次数: 63

摘要

虽然许多金属的烷氧化物早已为人所知,并被用作特定有机反应的催化剂,但直到1950年左右,这一学科才迅速发展起来(最后给出的315篇参考文献中,约有23篇属于1960年后的时期)。在下面的元素周期表中,烷氧化合物化学在过去二十年中受到关注的元素放在一个框架内,圈起来的是我们实验室也进行过研究的元素。最近出现了一些涉及该主题不同方面的评论文章(30-33、165、175、227、241、296)。
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Alkoxides and alkylalkoxides of metals and metalloids

Although alkoxides of a number of metals have been known and employed as catalysts for specific organic reactions for a long time, it is only since about 1950 that the subject has grown at a rapid pace (about 23rd of 315 references given at the end belong to the post-1960 period). In the periodic table given below, elements whose alkoxide chemistry has received attention during the last two decades are placed within a frame-work and the encircled ones are those on which work has been carried out in our laboratories also. A number of review articles (30–33, 165, 175, 227, 241, 296) dealing with different aspects of the subject have appeared recently.

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