水吸收法和水胺吸收法从沼气中提取二氧化碳的效率比较分析

Yu.V. Ivanov, H. Zhuk, L. Onopa, S.P. Krushnevych
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引用次数: 2

摘要

利用计算机模拟分析了目前应用最广泛的从沼气中提取二氧化碳的氨法和水法生产生物甲烷的能源成本。采用水胺联合吸附法对CO2净化沼气进行了对比分析。在CO2含量为32% ~ 42%的范围内,吸水法提取二氧化碳的比能成本平均比胺法低2.5倍,但由于其水溶性,吸水法的CH4损失为7.1 ~ 7.6%,胺法的CH4损失几乎为零,而水胺法的CH4损失不显著(0.17 ~ 2.8%)。利用预吸水的CO2节省的CH4可以补偿沼气压缩机的功耗或饱和胺吸收剂再生的热成本。这将允许减少能源消耗,几乎等于水的吸收1。从沼气中提取二氧化碳的模拟结果可用于优化生产生物甲烷的技术吸收方案。生物甲烷是一种天然气的类似物。圣经13,图5,表6。
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COMPARATIVE ANALYSIS OF THE EFFICIENCY OF WATER AND WATER-AMINE ABSORPTION PROCESSES FOR EXTRACTING CO2 FROM BIOGAS
The production of biomethane from biogas energy costsfor the most widely used amine and water processes for extracting carbon dioxide from biogas were analyzed using computer simulation. Combined water-amine absorption method of biogas purification from CO2 wasincluded in the comparative analysis. For the CO2 content of the biogas from 32 to 42 %, the specific energy costs when using water absorption to extract carbon dioxide from biogas are, on average, in ~ 2.5 times lower than amine absorption, but the loss of CH4 by water absorption was 7.1–7.6 % due to its watersolubility with practically zero CH4 loss when using amine absorption and insignificant loss (0.17–2.8 %) using water-amine technology. Using preliminary water absorption of CO2 saved CH4 can compensate the power consumption of the biogas compressor or the heatcosts of saturated amine absorbent regenerating. This will allowto reduce energy consumption to almost equal to water absorptionone. The results of simulation of carbon dioxide extraction from biogas can be used to optimize technological absorption schemes for the production of biomethane — an analogueof natural gas. Bibl. 13, Fig. 5, Tab. 6.
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