{"title":"CCl在顺式和反式4-t-丁基环己基氯中伸缩振动的红外强度","authors":"J.R. Hall , M.Kent Wilson","doi":"10.1016/0371-1951(66)80217-5","DOIUrl":null,"url":null,"abstract":"<div><p>Infrared intensity measurements of <em>cis</em> and <em>trans</em> isomers of 4-<em>t</em>-butylcyclohexyl chloride in CS<sub>2</sub> solution show that the apparent molecular extinction coefficient for the equatorial CCl stretching vibration is 60 percent greater than the value for the axial CCl stretching vibration. The integrated absorption intensity is 47 percent greater for the <em>trans</em> isomer. Dilute solutions of the individual isomers conformed to Beer's Law. No solute—solute interaction was observed for solutions of isomeric mixtures.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 10","pages":"Pages 1729-1732"},"PeriodicalIF":0.0000,"publicationDate":"1966-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80217-5","citationCount":"11","resultStr":"{\"title\":\"Infrared intensities of CCl stretching vibrations in cis- and trans-4-t-butylcyclohexyl chloride\",\"authors\":\"J.R. Hall , M.Kent Wilson\",\"doi\":\"10.1016/0371-1951(66)80217-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Infrared intensity measurements of <em>cis</em> and <em>trans</em> isomers of 4-<em>t</em>-butylcyclohexyl chloride in CS<sub>2</sub> solution show that the apparent molecular extinction coefficient for the equatorial CCl stretching vibration is 60 percent greater than the value for the axial CCl stretching vibration. The integrated absorption intensity is 47 percent greater for the <em>trans</em> isomer. Dilute solutions of the individual isomers conformed to Beer's Law. No solute—solute interaction was observed for solutions of isomeric mixtures.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 10\",\"pages\":\"Pages 1729-1732\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80217-5\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166802175\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166802175","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Infrared intensities of CCl stretching vibrations in cis- and trans-4-t-butylcyclohexyl chloride
Infrared intensity measurements of cis and trans isomers of 4-t-butylcyclohexyl chloride in CS2 solution show that the apparent molecular extinction coefficient for the equatorial CCl stretching vibration is 60 percent greater than the value for the axial CCl stretching vibration. The integrated absorption intensity is 47 percent greater for the trans isomer. Dilute solutions of the individual isomers conformed to Beer's Law. No solute—solute interaction was observed for solutions of isomeric mixtures.
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