添加辣木叶提取物合成壳聚糖-海藻酸盐多电解质复合膜的研究

Baiq Amelia Riyandari, Yupita Tri Rizki, M. Ramdani
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引用次数: 0

摘要

以壳聚糖和海藻酸盐为基质膜,加入辣木叶提取物合成聚电解质复合物(PEC)。研究了添加辣木叶提取物制备壳聚糖-海藻酸盐PEC膜的工艺。在日光下干燥除去水分制备克罗勒叶,用浸渍法提取干燥后的克罗勒叶。本研究使用的膜液最终浓度分别为0.0% (E0膜)、0.50% (E1膜)、0.75% (E2膜)和1.00% (E3膜)。在室温(±25℃)、膜液pH为±4.0条件下,添加kelor萃取物制备了PEC壳聚糖-海藻酸盐膜。傅里叶红外光谱表征结果表明,壳聚糖-海藻酸盐通过质子化成胺基(-NH3 +)和解离成羧酸基(-COO−)的分子相互作用形成壳聚糖-海藻酸盐PEC膜。傅里叶红外光谱也表明,在壳聚糖-海藻酸盐的PEC膜中加入克罗勒叶提取物后,膜的波数发生了偏移。证实了PEC壳聚糖-海藻酸盐膜之间的分子相互作用由于kelor提取物的存在而发生了变化,表明PEC壳聚糖-海藻酸盐膜与kelor提取物已经形成。扫描电镜(SEM)形貌分析显示,加入kelor提取物后,表面呈现多孔和非均质分布。
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SYNTHESIS OF POLYELECTROLYTE COMPLEX FILMS OF CHITOSAN-ALGINATE BY ADDITION OF KELOR LEAVES EXTRACT (Moringa oleifera) FOR FOOD PACKAGING
This research aims to synthesize the polyelectrolyte complex (PEC) using chitosan and alginate as matrix film with the addition of kelor leaves extract (Moringa oleifera). The preparation of PEC films of chitosan-alginate by addition of kelor leaves extract (Moringa oleifera) had been implemented. The kelor leaves was prepared by drying process under the sun for removing water content and the dried kelor leaves was extracted using maceration technique. The final concentrations of film solution used in this study were 0.0% (Film E0), 0.50% (Film E1), 0.75% (Film E2), and 1.00% (Film E3). The PEC chitosan-alginate films with addition of kelor extract were prepared in room temperature (± 25 °C) and pH of film solution was ± 4.0. The result of film’s characterization using FTIR spectrophotometer showed that PEC films of chitosan-alginate were formed through the molecular interaction between chitosan which protonated into amine groups (–NH3+) and alginate which dissociated into carboxylate groups (–COO−). Based on FTIR spectrum, it also showed that there were some wavenumber shifts after addition of kelor leaves extract into PEC films of chitosan-alginate. It was confirmed that there were the changing of molecular interaction between PEC chitosan-alginate films due to presence of kelor extract, indicating that PEC chitosan-alginate films with kelor extract had been formed. Morphological analysis using a scanning electron microscope (SEM) displayed both porous and heterogeneous distribution on the surface after addition of kelor extract.
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