衰变序列。带末端卤化物原子的聚全氟烷和聚全氟烷的质谱离子序列

A. Tyutyunov
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摘要

本报告介绍了聚全氟烷烃及其端卤化物衍生物的离子系列质谱。与离子系列的线性全氟烷烃及其衍生物的末端卤化物原子进行比较。讨论了由于链上氧原子的变化以及末端基团的结构引起的断裂变化。
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Decay sequences - ion series of mass spectra of polyoxaperfluoroalkanes and polyoxaperfluoroalkils with terminal halide atoms
: This report presents the ionic series of mass spectra of polyoxaperfluoroalkanes, as well as their derivatives with terminal halide atoms. In comparison with ionic series of linear perfluoroalkanes, as well as its derivatives with terminal halide atoms. Fragmentation changes due to oxygen atoms of the chain, as well as the structure of terminal groups, are discussed.
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