含Co分子筛的费托合成催化剂及其对烃类分子质量的影响

Reactions Pub Date : 2023-07-15 DOI:10.3390/reactions4030022
L. Sineva, V. Mordkovich, E. Asalieva, V.Ye. Smirnova
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引用次数: 1

摘要

该综述致力于研究旨在创造结合几种类型活性位点的催化剂的主题领域。同时,可以通过改变活性位点的强度和浓度以及位点间距离来控制费托合成产物的组成。通过对文献数据的对比分析,可以得出催化颗粒形成在FTS和酸催化烃类转化中活跃的主要原理:(1)弱Bronsted酸位点的存在控制裂解深度;(2)对烃类再吸附的Bronsted酸位点的可用性;(3)弱co -沸石相互作用减少甲烷生成。
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Zeolite-Containing Co Catalysts for Fischer–Tropsch Synthesis with Tailor-Made Molecular-Weight Distribution of Hydrocarbons
The review is dedicated to the topical field of research aimed at creating catalysts combining several types of active sites. At the same time, the composition of Fischer–Tropsch synthesis (FTS) products can be controlled by changing the strength and concentration of the active sites and inter-site distances. A comparative analysis of the literature data allows to formulate the main principles of catalytic particles formation active in FTS and acid-catalyzed transformations of hydrocarbons: (1) the presence of weak Bronsted acid sites to control the cracking depth, (2) an availability of Bronsted acid sites for re-adsorption hydrocarbons and (3) weak Co-zeolite interaction to reduce methane formation.
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