获得一种具有缓蚀剂性能的反相乳化剂

S. L. Vulfovich, N. A. Sergeeva, V. Ragulin, A. G. Telin, V. Dokichev
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引用次数: 0

摘要

反相乳剂广泛应用于石油生产过程;此外,由于具有许多独特的性能,它们既可用于钻井和压井,也可用于调平注入剖面,还可作为液体封隔器进行修复和隔离。大多数工业乳化剂属于由天然和合成的羧酸和胺(伯胺和仲胺)或氨基醇衍生的脂肪酸酰胺类。考虑到许多技术操作,例如用浓盐溶液压井(反乳液用作封堵液),用酸成分处理井底区域(反乳液用作酸转移剂),都伴随着金属设备的强烈腐蚀,并且需要额外的腐蚀抑制成本,我们为自己设定了开发具有缓蚀剂性能的反乳化剂的目标。以菜籽油和2-[(2-氨基乙基)氨基]乙醇为初始化合物,在碱的作用下进行催化反应,制得具有反乳乳化剂和缓蚀剂性能的氨基胺。叙述了合成条件,并对所得化合物的结构进行了证明。测定了其表面活性、乳化能力以及在二氧化碳腐蚀条件下的抑制活性。
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OBTAINING AN EMULSIFIER OF INVERSE EMULSIONS WITH A CORROSION INHIBITOR PROPERTIES
Reverse emulsions are widely used in oil production processes; moreover, due to a number of unique properties, they are used both in drilling and in killing wells, and for leveling the injectivity profile, as well as in repair and isolation works as a liquid packer. Most industrial emulsifiers belong to the class of fatty acid amides derived from natural and synthetic carboxylic acids and amines (primary and secondary) or amino alcohols. Given that many technological operations, such as killing with concentrated salt solutions (reverse emulsions are used as blocking fluids), treatment of the bottomhole zone with acid compositions (reverse emulsions are used as an acid diverter), are accompanied by intense corrosion of metal equipment and require additional costs for corrosion inhibition, we set ourselves the goal of developing an invert emulsifier with corrosion inhibitor properties. Using rapeseed oil and 2-[(2-aminoethyl)amino]ethanol as the initial compounds of the catalytic reaction under the action of alkali, amidoamine was obtained, which has the properties of an emulsifier of reverse emulsions and a corrosion inhibitor. Synthesis conditions are described and proof of the structure of the resulting compound is given. Its surface-active properties, emulsifying ability, as well as inhibitory activity under conditions of carbon dioxide corrosion were determined.
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来源期刊
CiteScore
0.80
自引率
50.00%
发文量
41
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