为生物医学应用量身定制mof:幻想还是具体的现实?生物友好机械合成Fe-BTC的实例研究

IF 3.8 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Comments on Inorganic Chemistry Pub Date : 2022-12-19 DOI:10.1080/02603594.2022.2153837

Giada Mannias, A. Scano, M. Pilloni, E. Magner, G. Ennas

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引用次数: 1

摘要

摘要:我们指出了铁(III)三聚酸金属有机框架的特殊可定制性，以适应生物友好的条件。这在生物医学应用的一锅固定化生物分子方面尤其具有吸引力。在室温下，通过机械化学方法在绿色，生物相容的条件下进行合成，无需额外的溶剂，只需1小时。与基于解决方案的方法相比，溶剂已被证明对于构建框架是不必要的。材料的微观结构和热稳定性不受ph的影响。相反，可以通过简单地改变碱的量来调整结构性能。图形abstracrt

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Tailoring MOFs to Biomedical Applications: A Chimera or a Concrete Reality? The Case Study of Fe-BTC by bio-friendly Mechanosynthesis

ABSTRACT We point-out an exceptional tailorability of iron(III) trimesate metal-organic framework to bio-friendly conditions. This is particularly attractive in sight of one-pot immobilization of biomolecules for biomedical applications. Synthesis is carried out via mechanochemical approach under green, biocompatible conditions without additional solvents, in just 1 hour, at room temperature. Solvents are proven to be unnecessary to build the framework, in contrast to solution-based methods. Microstructure and thermal stability of the material are not affected by pH. Conversely, textural properties can be tuned by simply varying the amount of base. Graphical abstracrt

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来源期刊

Comments on Inorganic Chemistry 化学-无机化学与核化学

CiteScore

9.00

自引率

1.90%

发文量

审稿时长

>12 weeks

期刊介绍： Comments on Inorganic Chemistry is intended as a vehicle for authoritatively written critical discussions of inorganic chemistry research. We publish focused articles of any length that critique or comment upon new concepts, or which introduce new interpretations or developments of long-standing concepts. “Comments” may contain critical discussions of previously published work, or original research that critiques existing concepts or introduces novel concepts. Through the medium of “comments,” the Editors encourage authors in any area of inorganic chemistry - synthesis, structure, spectroscopy, kinetics and mechanisms, theory - to write about their interests in a manner that is both personal and pedagogical. Comments is an excellent platform for younger inorganic chemists whose research is not yet widely known to describe their work, and add to the spectrum of Comments’ author profiles, which includes many well-established inorganic chemists.