3-三乙氧基硅丙胺(APTES)改性商品稻壳活性炭吸附CO2的研究

Muhammad Zubair Abdul Wahab Saaroni, H. Abdullah, E. E. Masiren, M. R. Khan
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引用次数: 3

摘要

二氧化碳是导致全球变暖的温室气体之一。因此,为了减少二氧化碳排放到大气中,需要二氧化碳捕获技术。以3-三乙氧基硅丙胺(APTES)为浸渍剂,研究了改性稻壳活性炭对CO2的吸附效果。考察了APTES浓度(2-5 wt%)、溶剂类型(水和乙醇)等改性参数。然后,对改性活性炭进行了氮吸附-脱附、扫描电镜和傅里叶变换红外光谱表征。以乙醇为溶剂,APTES浓度为5 wt %时,APTES- ac对CO2的最大吸附量为7602 mg/g。研究表明,经APTES改性的稻壳活性炭通过物理吸附和化学吸附两种方式提高了稻壳活性炭对CO2的吸附性能。二氧化碳是导致全球变暖的温室气体之一。因此,为了减少二氧化碳排放到大气中,需要二氧化碳捕获技术。以3-三乙氧基硅丙胺(APTES)为浸渍剂,研究了改性稻壳活性炭对CO2的吸附效果。考察了APTES浓度(2-5 wt%)、溶剂类型(水和乙醇)等改性参数。然后,对改性活性炭进行了氮吸附-脱附、扫描电镜和傅里叶变换红外光谱表征。以乙醇为溶剂,APTES浓度为5 wt %时,APTES- ac对CO2的最大吸附量为7602 mg/g。研究表明,经APTES改性的稻壳活性炭通过物理吸附和化学吸附两种方式提高了稻壳活性炭对CO2的吸附性能。
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CO2 adsorption using 3-triethoxysilylpropylamine (APTES)-modified commercial rice husk activated carbon
Carbon dioxide (CO2) is one of the greenhouse gases that cause global warming. Therefore, there is a need for CO2 capture technologies in order to reduce the CO2 emissions to the atmosphere. In this study, commercial rice husk activated carbon was impregnated with 3-triethoxysilylpropylamine (APTES) to investigate the efficiency of modified activated carbon for CO2 adsorption. The modification parameters, such as the APTES concentration (2-5 wt%) and the type of solvent (water and ethanol) were also investigated. Then, the modified activated carbon was characterized by nitrogen adsorption-desorption, scanning electron microscopy and Fourier transform infrared spectroscopy. The maximum CO2 adsorption capacity was 7602 mg/g for APTES-AC with 5 wt % APTES using ethanol as solvent. This study shows that the rice husk activated carbon modified with APTES could enhance the CO2 adsorption performance due to the physisorption and chemisorption.Carbon dioxide (CO2) is one of the greenhouse gases that cause global warming. Therefore, there is a need for CO2 capture technologies in order to reduce the CO2 emissions to the atmosphere. In this study, commercial rice husk activated carbon was impregnated with 3-triethoxysilylpropylamine (APTES) to investigate the efficiency of modified activated carbon for CO2 adsorption. The modification parameters, such as the APTES concentration (2-5 wt%) and the type of solvent (water and ethanol) were also investigated. Then, the modified activated carbon was characterized by nitrogen adsorption-desorption, scanning electron microscopy and Fourier transform infrared spectroscopy. The maximum CO2 adsorption capacity was 7602 mg/g for APTES-AC with 5 wt % APTES using ethanol as solvent. This study shows that the rice husk activated carbon modified with APTES could enhance the CO2 adsorption performance due to the physisorption and chemisorption.
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