N. Pajot, R. Papiernik, L. Hubert-Pfalzgraf, J. Vaissermann, S. Parraud
{"title":"金属辅助活化2-羟乙基甲基丙烯酸酯的C-O键。Ti5(OPri)9(µ-OPri)(µ，η2-OC2H4O)(µ3，η2-OC2H4O)3(µ4，η2-OC2H4O)的合成及分子结构","authors":"N. Pajot, R. Papiernik, L. Hubert-Pfalzgraf, J. Vaissermann, S. Parraud","doi":"10.1039/C39950001817","DOIUrl":null,"url":null,"abstract":"Ti5(OPri)9(µ-OPri)(OC2H4O)5 is formed by the reaction between Ti(OPri)4 and 2-hydroxyethylmethacrylate in toluene at room temperature; the pentanuclear aggregate is asymmetric with the titanium atoms displaying coordination numbers of five, six and seven.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"43 1","pages":"1817-1819"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"13","resultStr":"{\"title\":\"Metal-assisted activation of the C–O bond of 2-hydroxyethylmethacrylate. Synthesis and molecular structure of Ti5(OPri)9(µ-OPri)(µ,η2-OC2H4O)(µ3,η2-OC2H4O)3(µ4,η2-OC2H4O)\",\"authors\":\"N. Pajot, R. Papiernik, L. Hubert-Pfalzgraf, J. Vaissermann, S. Parraud\",\"doi\":\"10.1039/C39950001817\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Ti5(OPri)9(µ-OPri)(OC2H4O)5 is formed by the reaction between Ti(OPri)4 and 2-hydroxyethylmethacrylate in toluene at room temperature; the pentanuclear aggregate is asymmetric with the titanium atoms displaying coordination numbers of five, six and seven.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"43 1\",\"pages\":\"1817-1819\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"13\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001817\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001817","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Metal-assisted activation of the C–O bond of 2-hydroxyethylmethacrylate. Synthesis and molecular structure of Ti5(OPri)9(µ-OPri)(µ,η2-OC2H4O)(µ3,η2-OC2H4O)3(µ4,η2-OC2H4O)
Ti5(OPri)9(µ-OPri)(OC2H4O)5 is formed by the reaction between Ti(OPri)4 and 2-hydroxyethylmethacrylate in toluene at room temperature; the pentanuclear aggregate is asymmetric with the titanium atoms displaying coordination numbers of five, six and seven.
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