金属辅助活化2-羟乙基甲基丙烯酸酯的C-O键。Ti5(OPri)9(µ-OPri)(µ,η2-OC2H4O)(µ3,η2-OC2H4O)3(µ4,η2-OC2H4O)的合成及分子结构

N. Pajot, R. Papiernik, L. Hubert-Pfalzgraf, J. Vaissermann, S. Parraud
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引用次数: 13

摘要

Ti5(OPri)9(µ-OPri)(oc2h40o)5是由Ti(OPri)4与甲基丙烯酸2-羟乙酯在甲苯中室温反应生成的;五核聚集体是不对称的,钛原子的配位数为5、6和7。
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Metal-assisted activation of the C–O bond of 2-hydroxyethylmethacrylate. Synthesis and molecular structure of Ti5(OPri)9(µ-OPri)(µ,η2-OC2H4O)(µ3,η2-OC2H4O)3(µ4,η2-OC2H4O)
Ti5(OPri)9(µ-OPri)(OC2H4O)5 is formed by the reaction between Ti(OPri)4 and 2-hydroxyethylmethacrylate in toluene at room temperature; the pentanuclear aggregate is asymmetric with the titanium atoms displaying coordination numbers of five, six and seven.
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