W-LED用Sr3La(AlO)3(BO3)4:Eu3+,Sm3+荧光粉的合成及光致发光性能

IF 0.9 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Physics and Chemistry of Solid State Pub Date : 2023-03-27 DOI:10.15330/pcss.24.1.202-207
R. M. Yerojwar, N. Kokode, C. M. Nandanwar, D. Ingole
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引用次数: 11

摘要

采用燃烧法合成了Eu3+掺杂Sr3La(AlO)3(BO3)4和Sm3+掺杂Sr3La(AlO)3(BO3)4两种高效发红光的荧光粉,并对样品的光致发光性能进行了详细的研究。用扫描电镜观察其形貌,用CIE分析其色度。结果表明,Eu3+和Sm3+的激发波长从340 nm扩展到420 nm,其中最高激发波长(394 nm和406 nm)位于紫光区,表明该荧光粉与LED芯片具有良好的相关性。在394nm紫光激发下,Eu3+掺杂Sr3La(AlO)3(BO3)4和Sm3+掺杂Sr3La(AlO)3(BO3)4发出强红光,在406 nm紫光激发下,Sm3+掺杂Sr3La(AlO)3(BO3)4的主发射峰分别位于617 nm和602 nm。发光特性表明该荧光粉具有优异的稳定性。这些结果表明,Sr3La(AlO)3(BO3)4:Eu3+和Sr3La(AlO)3(BO3)4:Sm3+红色荧光粉在紫外激发下w - led中的重要性。
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Synthesis and Photoluminescence characterization of Sr3La(AlO)3(BO3)4:Eu3+,Sm3+ Phosphor for W-LED
A Red emitting with high efficiency Eu3+ doped Sr3La(AlO)3(BO3)4 and Sm3+ doped Sr3La(AlO)3(BO3)4 phosphors  has been synthesized by combustion method, meanwhile, the photoluminescence properties of samples are investigated in detail. Morphology by SEM and chromaticity by CIE was studied. The results show that the excitation extends from 340 nm to 420 nm, with the highest excitation (394 nm and 406 nm) being in the violet area for Eu3+ and Sm3+ doping, indicating that the phosphor can correlate well with LED chips. Under violet light excitation of 394nm the phosphor Eu3+ doped Sr3La(AlO)3(BO3)4 and of 406 nm the phosphor Sm3+ doped Sr3La(AlO)3(BO3)4 can emit strong red light showing main emission peaks located at 617 nm and 602 nm are observed respectively. The PL properties implies the excellent stability of the phosphor. These results imply that the importance red phosphors Sr3La(AlO)3(BO3)4:Eu3+  and Sr3La(AlO)3(BO3)4:Sm3+ in W-LEDs under NUV excitation.
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来源期刊
CiteScore
1.70
自引率
14.30%
发文量
83
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