纳米TiO2掺杂Nb作为PEMFC的新型载体

E. Valenzuela, V. Ramos-Sánchez, A. A. L. Arista, O. Savadogo
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引用次数: 7

摘要

目前,PEMFC的主要问题之一是耐久性问题。历史上,碳一直被用作PEMFC的催化剂载体;然而,在电池的环境条件下,碳被氧化,使催化剂不受支撑。为了提高催化剂在PEMFC中的稳定性和耐久性,提出了一种新型的纳米结构金属氧化物载体。在这项工作中,TiO2掺杂了Nb,以获得一种结合化学稳定性,高表面积和足够的电子导电性的材料,从而成为长期应用于PEMFC的成功的催化剂载体候选物。对TiO2-Nb纳米结构催化剂载体进行了物理和电化学表征。结果表明:TiO2-Nb具有较高的比表面积和良好的颗粒分散性;在高电位条件下,TiO2-Nb比碳更稳定,并对其电化学活性和稳定性进行了评价。
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Nanostructured TiO2 Doped with Nb as a Novel Support for PEMFC
Nowadays, one of the major issues of the PEMFC concerns the durability. Historically, carbon has been used as a catalyst support in PEMFC; nevertheless, under the environmental conditions of the cell, the carbon is oxidized, leaving the catalyst unsupported. In order to increase the stability and durability of the catalyst in the PEMFC, a novel nanostructured metallic oxide support is proposed. In this work, TiO2 was doped with Nb to obtain a material that combines chemical stability, high surface area, and an adequate electronic conductivity in order to be a successful catalyst support candidate for long-term PEMFC applications. The TiO2-Nb nanostructured catalyst support was physically and electrochemically characterized. According to the results, the TiO2-Nb offers high surface area and good particle dispersion; also, the electrochemical activity and stability of the support were evaluated under high potential conditions, where the TiO2-Nb proved to be much more stable than carbon.
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