E. Valenzuela, V. Ramos-Sánchez, A. A. L. Arista, O. Savadogo
{"title":"纳米TiO2掺杂Nb作为PEMFC的新型载体","authors":"E. Valenzuela, V. Ramos-Sánchez, A. A. L. Arista, O. Savadogo","doi":"10.1155/2013/706513","DOIUrl":null,"url":null,"abstract":"Nowadays, one of the major issues of the PEMFC concerns the durability. Historically, carbon has been used as a catalyst support in PEMFC; nevertheless, under the environmental conditions of the cell, the carbon is oxidized, leaving the catalyst unsupported. In order to increase the stability and durability of the catalyst in the PEMFC, a novel nanostructured metallic oxide support is proposed. In this work, TiO2 was doped with Nb to obtain a material that combines chemical stability, high surface area, and an adequate electronic conductivity in order to be a successful catalyst support candidate for long-term PEMFC applications. The TiO2-Nb nanostructured catalyst support was physically and electrochemically characterized. According to the results, the TiO2-Nb offers high surface area and good particle dispersion; also, the electrochemical activity and stability of the support were evaluated under high potential conditions, where the TiO2-Nb proved to be much more stable than carbon.","PeriodicalId":17611,"journal":{"name":"Journal: Materials","volume":"27 1","pages":"1-6"},"PeriodicalIF":0.0000,"publicationDate":"2013-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"Nanostructured TiO2 Doped with Nb as a Novel Support for PEMFC\",\"authors\":\"E. Valenzuela, V. Ramos-Sánchez, A. A. L. Arista, O. Savadogo\",\"doi\":\"10.1155/2013/706513\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Nowadays, one of the major issues of the PEMFC concerns the durability. Historically, carbon has been used as a catalyst support in PEMFC; nevertheless, under the environmental conditions of the cell, the carbon is oxidized, leaving the catalyst unsupported. In order to increase the stability and durability of the catalyst in the PEMFC, a novel nanostructured metallic oxide support is proposed. In this work, TiO2 was doped with Nb to obtain a material that combines chemical stability, high surface area, and an adequate electronic conductivity in order to be a successful catalyst support candidate for long-term PEMFC applications. The TiO2-Nb nanostructured catalyst support was physically and electrochemically characterized. According to the results, the TiO2-Nb offers high surface area and good particle dispersion; also, the electrochemical activity and stability of the support were evaluated under high potential conditions, where the TiO2-Nb proved to be much more stable than carbon.\",\"PeriodicalId\":17611,\"journal\":{\"name\":\"Journal: Materials\",\"volume\":\"27 1\",\"pages\":\"1-6\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-05-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal: Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2013/706513\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal: Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2013/706513","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Nanostructured TiO2 Doped with Nb as a Novel Support for PEMFC
Nowadays, one of the major issues of the PEMFC concerns the durability. Historically, carbon has been used as a catalyst support in PEMFC; nevertheless, under the environmental conditions of the cell, the carbon is oxidized, leaving the catalyst unsupported. In order to increase the stability and durability of the catalyst in the PEMFC, a novel nanostructured metallic oxide support is proposed. In this work, TiO2 was doped with Nb to obtain a material that combines chemical stability, high surface area, and an adequate electronic conductivity in order to be a successful catalyst support candidate for long-term PEMFC applications. The TiO2-Nb nanostructured catalyst support was physically and electrochemically characterized. According to the results, the TiO2-Nb offers high surface area and good particle dispersion; also, the electrochemical activity and stability of the support were evaluated under high potential conditions, where the TiO2-Nb proved to be much more stable than carbon.