用于聚合物研究的x射线和中子反射率

T.P. Russell
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引用次数: 551

摘要

本文回顾了用x射线和中子反射率来研究凝聚态和溶液中的聚合物。介绍了镜面反射率的基本理论和实验概念。讨论了中子和x射线反射率的应用研究,以及这些研究与聚合物科学中重要问题的相关性。这些包括在溶液和凝聚态下有序和无序均聚物和嵌段共聚物的研究。最后,讨论了非镜面扩散散射及其在聚合物科学中的潜在应用。
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X-ray and neutron reflectivity for the investigation of polymers

The use of X-ray and neutron reflectivity to study polymers in the condensed state and in solutions is revieved in this article. Basic theoretical and experimental concepts of specular reflectivity are presented. Research in the application of neutron and X-ray reflectivity is discussed along with the relevance of these studies to important issues in polymer science. These include investigations of ordered and disordered homopolymers and block copolymers in solution and in the condensed state. Finally, a discussion of off-specular, diffuse scattering is presented with its potential use in polymer science.

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