生物柴油老化的光谱监测

M. Svilans, Aivars Blūms, R. Kampare
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引用次数: 4

摘要

评价了吸收光谱法和荧光光谱法监测生物柴油老化的适用性。分析了加速老化实验中紫外/可见和红外光谱记录的变化,以及相应的生物柴油的化学和物理性质的变化,即诱导期、粘度和酸值。提出了一种评价荧光光谱数据的新方法。结果表明,荧光光谱在检测生物柴油早期老化过程中性能变化方面具有良好的灵敏度。为此,提出了一种基于荧光的生物柴油质量监测新方法。
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Spectroscopic Monitoring of Biodiesel Aging
The suitability of absorption and fluorescence spectroscopy for monitoring biodiesel aging is assessed. Changes recorded in the UV/VIS and IR spectra during accelerated aging experiments are analysed with respect to corresponding changes in a selection of chemical and physical properties of biodiesel, namely, induction period, viscosity and acid number. A novel approach for evaluating fluorescence spectral data is presented. It is determined that fluorescence spectroscopy provides excellent sensitivity for detecting changes in biodiesel properties during early aging. Thus, a new sensitive method based on fluorescence for monitoring the quality of biodiesel is proposed.
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