胺萃取回收钒(V)

L. Kurbatova, O. Koryakova, M. Valova
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引用次数: 0

摘要

研究了N-(2-羟基-5-壬基苄基)-β, β-二羟乙胺对钒(V)的萃取工艺,并考察了萃取剂浓度、温度、溶剂类型等因素对钒(V)的影响。从而确定了最佳提取条件。结果表明,钒(V)的萃取具有较高的分配系数,并且在有机相中形成了含有一个十氰酸阴离子和四个萃取剂分子的络合物。提取的钒(V)与胺配合物的稳定性在一个月以上。关键词:萃取,钒,分布系数,红外光谱
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Extraction Recovery of Vanadium(V) by Amines
The extraction of vanadium (V) by N-(2-hydroxy-5-nonylbenzyl)-β, β- dihydroxyethylamine was studied depending on different factors, such as pH of the medium, concentration of extracting agent, temperature and solvent type. This allowed the optimal extraction conditions to be determined. It was shown that extraction of vanadium (V) takes place with high distribution coefficients, and a complex containing a decavanadate anion and four molecules of the extractant is formed in the organic phase. The extracted vanadium (V) complex with amine is stable for more than one month. Keywords: extraction, vanadium, distribution coefficient, infrared spectroscopy
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