{"title":"混合气体在真实固体表面上的吸附:由于广义Langmuir-Freundlich等温线方程的广泛适用性，各种组分的吸附能之间缺乏相关性","authors":"W. Rudziński , A. Dominko , B.W. Wojciechowski","doi":"10.1016/S0923-0467(96)03118-1","DOIUrl":null,"url":null,"abstract":"<div><p>The Langmuir-Freundlich isotherm, generalized for mixed-gas adsorption on solids, is probably the most frequently applied equation in tecnological applications. A theoretical analysis of its origin suggests that this isotherm equation may be related to the situation when no correlations exist between the adsorption energies of various components. Some further modifications and improvements of this equation are proposed and tested.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"64 1","pages":"Pages 85-98"},"PeriodicalIF":0.0000,"publicationDate":"1996-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0923-0467(96)03118-1","citationCount":"10","resultStr":"{\"title\":\"Mixed-gas adsorption on real solid surfaces: Lack of correlations between adsorption energies of various components related to the wide applicability of the generalized Langmuir-Freundlich isotherm equation\",\"authors\":\"W. Rudziński , A. Dominko , B.W. Wojciechowski\",\"doi\":\"10.1016/S0923-0467(96)03118-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Langmuir-Freundlich isotherm, generalized for mixed-gas adsorption on solids, is probably the most frequently applied equation in tecnological applications. A theoretical analysis of its origin suggests that this isotherm equation may be related to the situation when no correlations exist between the adsorption energies of various components. Some further modifications and improvements of this equation are proposed and tested.</p></div>\",\"PeriodicalId\":101226,\"journal\":{\"name\":\"The Chemical Engineering Journal and the Biochemical Engineering Journal\",\"volume\":\"64 1\",\"pages\":\"Pages 85-98\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0923-0467(96)03118-1\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Chemical Engineering Journal and the Biochemical Engineering Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0923046796031181\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Chemical Engineering Journal and the Biochemical Engineering Journal","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0923046796031181","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mixed-gas adsorption on real solid surfaces: Lack of correlations between adsorption energies of various components related to the wide applicability of the generalized Langmuir-Freundlich isotherm equation
The Langmuir-Freundlich isotherm, generalized for mixed-gas adsorption on solids, is probably the most frequently applied equation in tecnological applications. A theoretical analysis of its origin suggests that this isotherm equation may be related to the situation when no correlations exist between the adsorption energies of various components. Some further modifications and improvements of this equation are proposed and tested.
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