纳米ZnO/木材复合材料的合成与性能研究

E. Tomina, A. Pavlenko, A. Dmitrenkov, S. Neminushchaya
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引用次数: 2

摘要

该研究的目的是合成氧化锌/银桦木纳米复合材料,并将其与未经改性的天然聚合物进行比较,评估其物理和机械性能。采用溶胶-凝胶法,我们合成了几乎为球形的无杂质氧化锌纳米颗粒,主要粒径约为20 nm。非晶态水合锌(OH)2浸渍在木材凝胶形成阶段。在木材中形成氧化锌纳米颗粒作为纳米反应器,导致氢氧化锌分解反应。ZnO/银桦木纳米复合材料表面的疏水性明显提高(润湿接触角增加一倍)。其防潮性和耐水性分别下降2-5倍和30%。与天然木材相比,纳米复合材料在径向(8-10倍)和切向(2.6-10倍)上的膨胀较小。
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Synthesis and properties of nanosized ZnO/wood composite
The aim of the study was to synthesise a ZnO/silver birch wood (Bétula péndula) nanocomposite and evaluate its physical and mechanical properties in comparison with an unmodified natural polymer.Using the sol-gel method, we synthesised almost spherical impurity-free zinc oxide nanoparticles with a predominant particle size of about 20 nm. Amorphous hydrated Zn(OH)2 was impregnated into the wood material at the gel formation stage. It resulted in the reaction of zinc hydroxide decomposition with the formation of ZnO nanoparticles in the wood as a nanoreactor.The hydrophobic properties of the surface of ZnO/silver birch wood nanocomposite improved significantly (the contact angle of wetting doubled). Its moisture and water resistance decreased (2-5 times and 30%, respectively). The nanocomposite also showed less swelling in the radial (8-10 times) and tangential (2.6-10 times) directions in comparison with natural wood.
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