垃圾填埋气体中的天然气

E. Pilarczyk, K.-D. Henning, K. Knoblauch
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引用次数: 18

摘要

基于活性炭的应用,开发了一种特殊的碳分子筛CMSC吸附工艺,用于净化垃圾填埋气体并随后回收替代天然气。通过使用不同的活性炭,微量污染物(如硫化氢、氨、汞、卤化烃、高级烷烃和芳烃)可从垃圾填埋气体中去除。净化后的气体可以通过分子筛CMSC变压吸附工艺处理成天然气。吸附工艺不仅适用于垃圾填埋气体,也适用于污水处理厂和生物反应器。这个过程是干燥的,几乎不需要维护。目前,在德意志联邦共和国和荷兰有几个试点和示范工厂正在运作。现在,荷兰正在考虑为各种垃圾填埋场和废水处理厂建设几个工业规模的工厂,其气体流量高达1,500立方米/小时(STP)。碳分子筛CMSC变压吸附工艺与相竞争的洗涤和隔膜工艺相比,具有一定的优势,有望在不久的将来实现技术上的应用。
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Natural gas from landfill gases

Based on the application of activated carbon, and a special carbon molecular sieve CMSC adsorption processes for the purification of landfill gases and subsequent recovery of substitute natural gas have been developed. By using different activated carbons trace contaminations (e.g. hydrogen sulfide, ammonia, mercury, halogenated hydrocarbons, higher alkanes and aromatics) are removed from landfill gas. The cleaned gas can then be processed by means of a pressure-swing adsorption process using molecular sieve CMSC into natural gas.

The adsorption processes can not only be applied to landfill gases but also waste water treatment plants and bioreactors. The processes are dry and almost maintenance-free. At the moment several pilot and demonstration plants are in operation in the Federal Republic of Germany and the Netherlands. Now several industrial-scale plants with gas flows of up to 1,500 m3/h (STP) are under consideration for various Dutch landfill sites and waste water treatment plants.

Compared to the competing scrubbing and diaphragm processes the pressure-swing adsorption process using the carbon molecular sieve CMSC has some essential advantages and technical realization can be expected in the near future.

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Publisher's note Contents Fermentable sugars from biopolymers of bagasse The history of refuse-derived fuels Biomass regenerable energy: edited by D.O. Hall and R.P. Overend, John Wiley & Sons, New York, NY, 1987, ix +504 pp., cloth, $65
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