{"title":"新型含能材料3,5 -二硝基氨基- 1,2,4 -三唑肼的合成及性能研究","authors":"周诚, 王伯周, 霍欢, 周群, 杨威, 叶志虎","doi":"10.3969/J.ISSN.1006-9941.2014.04.027","DOIUrl":null,"url":null,"abstract":"A novel energetic material,hydrazinium 3,5-dinitroamino-1,2,4-triazole( HDN AT) was designed and synthesized for the first time via condensation,nitrification and hydrazinolysis reaction w ith a total yield of 63. 69%. It's structure w as characterized by1 H N M R,13 C N M R,FT-IR and elemental analysis. In addition,some main properties of physico-chemistry and detonation for HDN AT w ere obtained by test or calculation. R esults show that its density is 1. 89 g·cm- 3,melting point 194-196 ℃,friction sensitivity 92%,impact sensitivity 100%,H5026. 8 cm,detonation velocity 9000 m·s- 1( ρ =1.80 g·cm- 3)and detonation pressure 36. 0 GPa calculated w ith VLM method.","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2014-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A Novel Energetic Material Hydrazinium 3, 5-Dinitroamino-1, 2, 4-triazole:Synthesis and Properties\",\"authors\":\"周诚, 王伯周, 霍欢, 周群, 杨威, 叶志虎\",\"doi\":\"10.3969/J.ISSN.1006-9941.2014.04.027\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel energetic material,hydrazinium 3,5-dinitroamino-1,2,4-triazole( HDN AT) was designed and synthesized for the first time via condensation,nitrification and hydrazinolysis reaction w ith a total yield of 63. 69%. It's structure w as characterized by1 H N M R,13 C N M R,FT-IR and elemental analysis. In addition,some main properties of physico-chemistry and detonation for HDN AT w ere obtained by test or calculation. R esults show that its density is 1. 89 g·cm- 3,melting point 194-196 ℃,friction sensitivity 92%,impact sensitivity 100%,H5026. 8 cm,detonation velocity 9000 m·s- 1( ρ =1.80 g·cm- 3)and detonation pressure 36. 0 GPa calculated w ith VLM method.\",\"PeriodicalId\":35753,\"journal\":{\"name\":\"Hanneng Cailiao/Chinese Journal of Energetic Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-08-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Hanneng Cailiao/Chinese Journal of Energetic Materials\",\"FirstCategoryId\":\"1087\",\"ListUrlMain\":\"https://doi.org/10.3969/J.ISSN.1006-9941.2014.04.027\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Hanneng Cailiao/Chinese Journal of Energetic Materials","FirstCategoryId":"1087","ListUrlMain":"https://doi.org/10.3969/J.ISSN.1006-9941.2014.04.027","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 1
摘要
通过缩合、硝化和肼解反应,首次设计合成了一种新型含能材料- 3,5-二硝基氨基-1,2,4-三唑肼(HDN AT),总产率为63。69%。其结构由1h N M R、13c N M R、FT-IR和元素分析表征。此外,还通过试验和计算得到了HDN AT的一些主要理化性能和爆轰性能。R结果表明其密度为1。89 g·cm- 3,熔点194-196℃,摩擦灵敏度92%,冲击灵敏度100%,H5026。8 cm,爆速9000 m·s- 1(ρ =1.80 g·cm- 3),爆压36。用VLM法计算出的GPa。
A Novel Energetic Material Hydrazinium 3, 5-Dinitroamino-1, 2, 4-triazole:Synthesis and Properties
A novel energetic material,hydrazinium 3,5-dinitroamino-1,2,4-triazole( HDN AT) was designed and synthesized for the first time via condensation,nitrification and hydrazinolysis reaction w ith a total yield of 63. 69%. It's structure w as characterized by1 H N M R,13 C N M R,FT-IR and elemental analysis. In addition,some main properties of physico-chemistry and detonation for HDN AT w ere obtained by test or calculation. R esults show that its density is 1. 89 g·cm- 3,melting point 194-196 ℃,friction sensitivity 92%,impact sensitivity 100%,H5026. 8 cm,detonation velocity 9000 m·s- 1( ρ =1.80 g·cm- 3)and detonation pressure 36. 0 GPa calculated w ith VLM method.
期刊介绍:
Chinese Journal of Energetic Materials is a vital forum for the exchange of science and technology in energetic materials, and information on - Propellants - Explosives - Pyrotechnics - Ignition, combustion and detonation